Structure of Fe3O complexes with long alkyl chain fatty acid, [Fe3O(O2CCnH2n+1)6L3]NO3 (L = H2O, n = 11, 13, 15, 17; L = py, n = 13, 15, 17);: crystal structure of [Fe3O(O2CC13H27)6(py)3]NO3

被引：16
|
作者：
Nakamoto, T [1 ]
Katada, M
Endo, K
Sano, H
机构：
[1] Japan Atom Energy Res Inst, Adv Sci Res Ctr, Tokai, Ibaraki 3191195, Japan
[2] Tokyo Metropolitan Univ, Radioisotope Res Ctr, Tokyo 1920397, Japan
[3] Showa Coll Pharmaceut Sci, Tokyo 1948543, Japan
[4] Otsuma Womens Univ, Sch Social Informat Studies, Dept Environm Sci, Tokyo 2068540, Japan
来源：
POLYHEDRON | 1998年 / 17卷 / 20期
关键词：
trinuclear iron complex; long alkyl chain carboxylate complex;
D O I：
10.1016/S0277-5387(98)00138-7
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two series of trinuclear iron(III) carboxylate complexes with long alkyl chains, [Fe3O(O2CR)(6)L-3]NO3 where L=H2O or py (pyridine), were prepared. Powder X-ray diffraction patterns of each series suggested that the aqua series has a double-layer structure and the pyridine series has a single-layer structure. The single crystal X-ray structure determination of [Fe3O(O2CC13H27)(6)(py)(3)]NO3 revealed that the compound forms a single-layer structure with the interlamellar orientation of alkyl chains being arranged alternately to those of adjacent layers. (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：3507 / 3514
页数：8
相关论文
共 50 条
  • [1] Structural transition at 225 K of the trinuclear Fe(III) heptanoate [Fe3O(O2CC6H13)6(H2O)3]NO3
    François, M
    Saleh, MI
    Rabu, P
    Souhassou, M
    Malaman, B
    Steinmetz, J
    [J]. SOLID STATE SCIENCES, 2005, 7 (10) : 1236 - 1246
  • [2] Cyclic voltammetric study of the trinuclear complexes [Fe3O(CH3COO)6(H2O)3]NO3 and [Fe3O(+H3NCH2COO-)6(H2O3]NO3)7
    Storch, H
    Constantinescu, E
    Andrei, M
    Dima, G
    Turta, C
    Lazarescu, A
    [J]. REVUE ROUMAINE DE CHIMIE, 2002, 47 (1-2) : 67 - 70
  • [3] Intermediate frustration in [Fe3O(CH3COO)6(H2O)3] NO3 • 4(H2O) trinuclear cluster
    Filoti, G
    Bartolome, J
    Dickson, DPE
    Rillo, C
    Prisecaru, I
    Jovmir, T
    Kuncser, V
    Turta, C
    [J]. JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 1999, 196 : 561 - 563
  • [4] 三核苯甲酸铁配合物［Fe3O(OBZ)6(H2O)3］(NO3)(a
    付德刚
    王国雄
    唐雯霞
    郁开北
    [J]. 无机化学学报, 1994, (01) : 63 - 68
  • [5] Synthesis and crystal structure of KNa3[Fe3O(CH3COO)6(H2O)2]3 [α-P2W17Fe(H2O)O61]·32.5H2O
    N. V. Izarova
    M. N. Sokolov
    A. V. Virovets
    H. G. Platas
    V. P. Fedin
    [J]. Journal of Structural Chemistry, 2005, 46 : 147 - 153
  • [6] [Fe3O(Ala)6(H2O)3](ClO4)7和[Fe3O(Gly)6(H2O)3](NO3)7·3H2O的顺磁共振谱及变温磁化率研究
    姚尚锋
    李健民
    [J]. 光谱实验室, 2002, (02) : 153 - 156
  • [7] Synthesis and crystal structure of KNa3[Fe3O(CH3COO)6(H2O)2]3[α-P2W17Fe(H2O)O61]•32.5H2O
    Izarova, NV
    Sokolov, MN
    Virovets, AV
    Platas, HG
    Fedin, VP
    [J]. JOURNAL OF STRUCTURAL CHEMISTRY, 2005, 46 (01) : 147 - 153
  • [8] Synthesis and Structure of [Fe3O(O2CCH2OMe)6(H2O)3][FeCl4]
    Douglas Ogrin
    Andrew R. Barron
    [J]. Journal of Chemical Crystallography, 2009, 39 : 68 - 72
  • [9] Synthesis and Structure of [Fe3O(O2CCH2OMe)6(H2O)3][FeCl4]
    Ogrin, Douglas
    Barron, Andrew R.
    [J]. JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2009, 39 (01) : 68 - 72
  • [10] Study of the [Fe3O(C8H7COO)6(H2O)3]NO3 complex by cyclic voltammetry
    Storch, H
    Constantinescu, E
    [J]. REVUE ROUMAINE DE CHIMIE, 2004, 49 (3-4) : 339 - 343
12345