The Double Role of Ionic Liquids in Electroorganic Synthesis: Green Solvents and Precursors of N-Heterocyclic Carbenes

被引：19
|
作者：
Feroci, Marta [1 ]
Orsini, Monica [2 ]
Rossi, Leucio [3 ]
Inesi, Achille [1 ]
机构：
[1] Sapienza Univ Rome, Dept Foundamental & Appl Sci Engn SBAI, I-00161 Rome, Italy
[2] Univ Roma Tre, Dept Elettron Applicata, I-00146 Rome, Italy
[3] Univ Aquila, Dipartimento Chim Ingn Chim & Mat, I-67040 Laquila, Italy
来源：
CURRENT ORGANIC SYNTHESIS | 2012年 / 9卷 / 01期
关键词：
Green chemistry; room temperature ionic liquids; N-heterocyclic carbenes; organocatalysts; electroorganic synthesis; DISSOCIATIVE ELECTRON-TRANSFER; SELECTIVE ELECTROCHEMICAL FLUORINATION; CARBON-HALOGEN BOND; HOMOGENEOUS CATALYSIS; REDUCTIVE CLEAVAGE; ELECTROCATALYTIC DIMERIZATION; ORGANIC ELECTROSYNTHESIS; ATOM ECONOMY; DIOXIDE; REACTIVITY;
D O I：
10.2174/157017912798889206
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Frequently, in spite of the use of a green reagent (the electron), the electrochemical methodologies are unable, owing to the presence of VOCs-supporting electrolytes solutions, to suggest very eco-friendly and competitive procedures of organic synthesis. In this paper, the possible utilization of room temperature ionic liquids, RTILs, as environmental-friendly solvents, instead of volatile and toxic solvents VOCs containing massive quantities of supporting electrolytes, has been reported. In addition, some new procedures of electroorganic synthesis, concerning the double role of RTILs as green solvents and precursors of electrogenerated N-heterocyclic carbenes (as organocatalysts and bases) have been emphasized.
引用
收藏
页码：40 / 52
页数：13
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