A linear metal-metal bonded tri-iron single-molecule magnet

被引：11

作者：

Srinivasan, Anandi ^{[1
]}

Musgrave, Rebecca A. ^{[1
]}

Rouzieres, Mathieu ^{[1
]}

Clerac, Rodolphe ^{[1
]}

McGrady, John E. ^{[2
]}

Hillard, Elizabeth A. ^{[1
,3
]}

机构：

[1] Univ Bordeaux, Ctr Rech Paul Pascal, CNRS, UMR 5031, F-33600 Pessac, France

[2] Univ Oxford, Dept Chem, South Parks Rd, Oxford OX1 3QZ, England

[3] CNRS, ICMCB, UMR 5026, 87 Ave Schweitzer, F-33608 Pessac, France

来源：

CHEMICAL COMMUNICATIONS | 2021年 / 57卷 / 98期

基金：

欧盟地平线“2020”;

关键词：

DINUCLEAR COMPOUNDS; MIXED-VALENCE; COMPLEXES; ABSORPTION;

D O I：

10.1039/d1cc05043e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The linear trinuclear complex cation [Fe-3(DpyF)(4)](2+) was prepared as [Fe-3(DpyF)(4)](BF4)(2)center dot 2CH(3)CN. With large Fe-Fe distances of 2.78 angstrom, this complex demonstrates intramolecular ferromagnetic coupling between the anisotropic Fe-II centers (J/k(B) = +20.9(5) K) giving an S-T = 6 ground state and exhibits single-molecule magnet properties.

引用

页码：13357 / 13360

页数：4

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