Schincalide A, a Schinortriterpenoid with a Tricyclo[5.2.1.011,6]decane-Bridged System from the Stems and Leaves of Schisandra incarnate

被引：24

作者：

Zhou, Ming ^{[1
]}

Liu, Ye ^{[1
]}

Song, Jian ^{[1
]}

Peng, Xiao-Gang ^{[1
]}

Cheng, Qi ^{[1
]}

Cao, Hui ^{[1
]}

Xiang, Ming ^{[1
]}

Ruan, Han-Li ^{[1
]}

机构：

[1] Huazhong Univ Sci & Technol, Tongji Med Coll, Hubei Key Lab Nat Med Chem & Resource Evaluat, Fac Pharm, Wuhan 430030, Peoples R China

来源：

ORGANIC LETTERS | 2016年 / 18卷 / 18期

关键词：

NIGRANOIC ACID; TRITERPENOIDS; GLAUCESCENS; LIGNANS; NORTRITERPENOIDS; LANCIFOLIA; FRUITS; FAMILY;

D O I：

10.1021/acs.orglett.6b02197

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Schincalide A (1), an unprecedented schinortriterpenoid possessing a tricyclo [5.2.1.0(1,6)] decane-bridged system, was isolated from the stems and leaves of Schisandra incarnate. The structure with absolute configuration of 1 was determined by extensive spectroscopic analyses and single-crystal X-ray diffraction. A hypothetical biosynthetic pathway of 1 was postulated.

引用

页码：4558 / 4561

页数：4