Vertically aligned silicon/carbon nanotube (VASCNT) arrays: Hierarchical anodes for lithium-ion battery

被引:94
|
作者
Wang, Wei [2 ]
Epur, Rigved [2 ]
Kumta, Prashant N. [1 ,2 ,3 ]
机构
[1] Univ Pittsburgh, Dept Bioengn, Dept Chem & Petr Engn, Pittsburgh, PA 15261 USA
[2] Univ Pittsburgh, Dept Mech Engn & Mat Sci, Pittsburgh, PA 15261 USA
[3] Univ Pittsburgh, Ctr Complex Engineerd Multifunct Mat, Pittsburgh, PA 15261 USA
基金
美国国家科学基金会;
关键词
Lithium-ion battery; Silicon; Anode; Carbon nanotubes; CVD; HIGH-CAPACITY; CARBON NANOTUBES; NANOWIRES; ROPES;
D O I
10.1016/j.elecom.2011.02.012
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Vertically aligned silicon/carbon nanotube arrays are directly synthesized on Inconel metal current collector as lithium-ion battery anode. The hierarchical anode eliminates the traditional preparation of electrodes obviating the use of polymer binder facilitating the desired lithium ion and electron kinetics in the electrode. The simple approach demonstrates a facile non-template way to prepare integrated anode architectures. The as synthesized anode demonstrates stable capacity similar to 2000 mAhg(-1) with only 6% irreversible loss observed in the first cycle. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:429 / 432
页数:4
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