Electrochemical synthesis and characterization of conducting copolymer: poly(o-anisidine-co-o-toluidine)

被引：9
|
作者：
Borole, DD [1 ]
Kapadi, UR [1 ]
Mahulikar, PP [1 ]
Hundiwale, DG [1 ]
机构：
[1] N Maharashtra Univ, Sch Chem Sci, Jalgaon 425001, MS, India
来源：
JOURNAL OF MATERIALS SCIENCE | 2005年 / 40卷 / 20期
关键词：
D O I：
10.1007/s10853-005-1999-3
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Copolymerization of o-anisidine and o-toluidine was achieved electrochemically in aqueous solution containing H2SO4 as supporting electrolyte. The copolymer compositions can be altered by varying the monomer feed ratios during electrosynthesis. The films were electropolymerized in solution containing monomers in various ratio (0.025-0.1 M) and 1 M sulphuric acid as electrolyte by applying sequential linear potential scan rate 50 mV/s between -0.2 to 1.0 V. versus Ag/AgCl electrode. The copolymers were characterized by cyclic voltammetric, conductivity measurement, UV-Visible spectroscopy, differential scanning calorimetry (DSC), thermogravimetric analysis (TGA). (c) 2005 Springer Science + Business Media, Inc.
引用
收藏
页码：5499 / 5506
页数：8
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