Spontaneous resolution of four-coordinate Zn(II) complexes in the formation of three-dimensional metal-organic frameworks

被引：31
|
作者：
Liu, Wen-Ting [1 ]
Ou, Yong-Cong [1 ]
Lin, Zhuo-jia [1 ,2 ]
Tong, Ming-Liang [1 ]
机构：
[1] Sun Yat Sen Univ, State Key Lab Optoelect Mat & Technol, Key Lab Bioinorgan & Synthet Chem, Sch Chem & Chem Engn,Minist Educ, Guangzhou 510275, Guangdong, Peoples R China
[2] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China
来源：
CRYSTENGCOMM | 2010年 / 12卷 / 11期
关键词：
HELICAL COORDINATION POLYMERS; ACHIRAL LIGANDS; CRYSTALLIZATION; TETRANUCLEAR; INDUCTION; NETWORK; DESIGN; STATE; ACID;
D O I：
10.1039/c0ce00206b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The three-dimensional chiral helical framework of the four-coordinate zinc complexes, [Zn(bdt)](n) (1a and 1b) (H(2)bdt = 1,4-benzeneditetrazol-5-yl), has been prepared via hydrothermal reaction. At the chiral centers, the tetrahedral zinc centers link with bdt ligands to form a chiral unc-type network, which exhibits an intense blue emission and spontaneous chiral resolution. The enantiomers of 1a and 1b have been confirmed by solid-state circular dichroism spectra.
引用
收藏
页码：3487 / 3489
页数：3
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