Preparation, Structure, and Reactions of Trifluoroacetimidoyl Palladium(II) Complexes

被引：15

作者：

Amii, Hideki ^{[1
,2
]}

Kageyama, Katsuhiko ^{[1
]}

Kishikawa, Yosuke ^{[1
]}

Hosokawa, Tsuyoshi ^{[1
]}

Morioka, Ryo ^{[2
]}

Katagiri, Toshimasa ^{[1
]}

Uneyama, Kenji ^{[1
]}

机构：

[1] Okayama Univ, Fac Engn, Dept Appl Chem, Okayama 7008530, Japan

[2] Gunma Univ, Grad Sch Engn, Dept Chem & Chem Biol, Kiryu, Gunma 3768515, Japan

来源：

ORGANOMETALLICS | 2012年 / 31卷 / 04期

关键词：

TRANSITION-METAL-COMPLEXES; CROSS-COUPLING REACTIONS; COPPER-CATALYZED TRIFLUOROMETHYLATION; ISOCYANIDE INSERTION REACTIONS; F REDUCTIVE ELIMINATION; PUSH-PULL CARBENES; IMIDOYL CHLORIDES; MEDIATED TRIFLUOROMETHYLATION; ORGANOMETALLIC COMPOUNDS; OXIDATIVE ADDITION;

D O I：

10.1021/om201021b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Trifluoroacetimidoyl metal complexes are useful intermediates for the selective synthesis of organofluorine compounds. Herein, we report preparations, structures, and reactions of fluorinated imidoyl palladium complexes. Oxidative addition of trifluoroacetimidoyl halides to Pd(PPh3)(4) afforded quantitatively the imidoyl palladium(II) complexes with phosphine ligands. The reaction of trifluoroacetimidoyl iodides with Pd-2(dba)(3) provided the phosphine-free imidoyl palladium complex in high yields. The X-ray crystal structure analysis of the phosphine-free complex [Pd(mu-I){mu-C(CF3)=N(PMP)}](4) revealed a cyclic tetranuclear structure containing the imidoyl and iodo bridges. The generation of aminotrifluoromethylcarbene equivalents by protonation or electrophilic alkylation of imidoyl palladium(II) complexes is discussed.

引用

页码：1281 / 1286

页数：6

共 50 条

[31] PREPARATION AND REACTIONS OF TRIETHYLPHOSPHINE COMPLEXES OF ZEROVALENT NICKEL, PALLADIUM, AND PLATINUM
SCHUNN, RA
INORGANIC CHEMISTRY, 1976, 15 (01) : 208 - 212
[32] Palladium(II) complexes with tris(2-carboxyethyl)phosphine, structure, reactions and cytostatic activity
Pruchnik, Hanna
Lis, Tadeusz
Latocha, Malgorzata
Zielinska, Aleksandra
Pruchnik, Florian P.
JOURNAL OF INORGANIC BIOCHEMISTRY, 2016, 156 : 14 - 21
[33] PREPARATION OF PD(II) ENOLATE COMPLEXES AND THEIR REACTIONS
ITO, Y
NAKATSUKA, M
KISE, N
SAEGUSA, T
TETRAHEDRON LETTERS, 1980, 21 (30) : 2873 - 2876
[34] Synthesis, Structure and Catalytic Activity of Three Organophosphine Bromo Palladium(II) Complexes for Coupling Reactions
Ju Shao-Ying
Li Xue
Gao An-Li
Jiang Jing
Yu Juan
Liu Wei-Ping
CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2021, 37 (05) : 785 - 790
[35] PALLADIUM-CATALYZED COUPLING REACTIONS OF TRIFLUOROACETIMIDOYL IODIDES WITH OLEFINS AND 1-ALKYNES
UNEYAMA, K
WATANABE, H
TETRAHEDRON LETTERS, 1991, 32 (11) : 1459 - 1462
[36] CYCLIC CARBENE-PALLADIUM(II) COMPLEXES DERIVED FROM THE REACTIONS OF ISOCYANIDE-PALLADIUM(II) COMPLEXES WITH NITRILIMINES AND NITRILYLIDES
FUCHITA, Y
HIDAKA, K
MORINAGA, S
HIRAKI, K
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1981, 54 (03) : 800 - 804
[37] REACTIONS OF CARBON-DIOXIDE WITH DIALKYL COMPLEXES OF PALLADIUM(II)
ITO, T
TSUCHIYA, H
YAMAMOTO, A
CHEMISTRY LETTERS, 1976, (08) : 851 - 854
[38] Reactions of cationic palladium(II) methyl and vinyl complexes with alkynes
LaPointe, AM
Brookhart, M
ORGANOMETALLICS, 1998, 17 (08) : 1530 - 1537
[39] Reactions of molecular oxygen with alkyl and hydride complexes of palladium(II)
Denney, MC
Smythe, NA
Cetto, KL
Kemp, RA
Goldberg, KI
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2005, 230 : U2149 - U2149
[40] THE REACTIONS OF TRIDENTATE CATIONIC PALLADIUM(II) COMPLEXES WITH OLEFINS AND NUCLEOPHILES
KRAATZ, HB
MILSTEIN, D
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 488 (1-2) : 223 - 232

← 1 2 3 4 5 →