New Calcium Ion Conducting Solid Electrolyte with NASICON-type Structure

被引：13
|
作者：
Lee, Wonrak [1 ]
Tamura, Shinji [1 ]
Imanaka, Nobuhito [1 ]
机构：
[1] Osaka Univ, Fac Engn, Dept Appl Chem, 2-1 Yamadaoka, Suita, Osaka 5650871, Japan
来源：
CHEMISTRY LETTERS | 2017年 / 46卷 / 10期
基金：
日本学术振兴会;
关键词：
Solid electrolyte; Calcium ion; NASICON-type structure; SYSTEM;
D O I：
10.1246/cl.170634
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Divalent calcium ion conducting solid electrolyte with three-dimensional NASICON-type structure, (CaxHf1-x)(4/(4-2x))Nb(PO4)(3), was successfully developed by introducing Ca2+ cations into HfNb(PO4)(3) as mother solid. The existence of three kinds of high valence cation, Hf4+, Nb5+, and P5+, in the structure successfully realized the effective reduction of electrostatic interaction functioned to Ca2+ in the structure. The (Ca0.05Hf0.95)(4/3.9)Nb(PO4)(3) solid showed considerably higher Ca2+ cation conductivity and lower activation energy than those of previously reported NASICON-type Ca0.5Zr2(PO4)(3) solid.
引用
收藏
页码：1486 / 1489
页数：4
相关论文
共 50 条
  • [41] Preparation and infiltration of NASICON-type solid electrolytes with microporous channels
    Lu, Xiaojuan
    Hai, Jiankang
    Zhang, Feng
    Li, Xinyu
    Li, Jing
    [J]. CERAMICS INTERNATIONAL, 2022, 48 (02) : 2203 - 2211
  • [42] Assessing the Electrochemical Stability Window of NASICON-Type Solid Electrolytes
    Benabed, Yasmine
    Rioux, Maxime
    Rousselot, Steeve
    Hautier, Geoffroy
    Dolle, Mickael
    [J]. FRONTIERS IN ENERGY RESEARCH, 2021, 9
  • [43] Investigation of Solid Polymer Electrolytes for NASICON-Type Solid-State Symmetric Sodium-Ion Battery
    Vasudevan, Sudharshan
    Dwivedi, Sushmita
    Babu, Karthick Babu Morekonda Ganesh
    Balaya, Palani
    [J]. ACS APPLIED MATERIALS & INTERFACES, 2024, 16 (38) : 50736 - 50746
  • [44] Li-ion transport studies of NASICON-type LiZr2(PO4)3 solid electrolyte crystallizing in rhombohedral structure at room temperature
    Khatua, Sumit
    Rao, Y. Bhaskara
    Achary, K. Ramakrushna
    Patro, L. N.
    [J]. SURFACES AND INTERFACES, 2023, 41
  • [45] Synthesis and characterization of divalent ion conductors with NASICON-type structures
    Lee, Wonrak
    Tamura, Shinji
    Imanaka, Nobuhito
    [J]. JOURNAL OF ASIAN CERAMIC SOCIETIES, 2019, 7 (02): : 221 - 227
  • [46] Correlated Migration Invokes Higher Na+-Ion Conductivity in NaSICON-Type Solid Electrolytes
    Zhang, Zhizhen
    Zou, Zheyi
    Kaup, Kavish
    Xiao, Ruijuan
    Shi, Siqi
    Avdeev, Maxim
    Hu, Yong-Sheng
    Wang, Da
    He, Bing
    Li, Hong
    Huang, Xuejie
    Nazar, Linda F.
    Chen, Liquan
    [J]. ADVANCED ENERGY MATERIALS, 2019, 9 (42)
  • [47] Synthesis and Properties of NaSICON-type LATP and LAGP Solid Electrolytes
    DeWees, Rachel
    Wang, Hui
    [J]. CHEMSUSCHEM, 2019, 12 (16) : 3713 - 3725
  • [48] Synthesis of a new NASICON-type blue luminescent material
    Masui, Toshiyuki
    Koyabu, Kazuhiko
    Tamura, Shinji
    Imanaka, Nobuhito
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2006, 418 (1-2) : 73 - 76
  • [49] Effect of microstructure on the conductivity of a NASICON-type lithium ion conductor
    Johnson, Paul
    Sammes, Nigel
    Imanishi, Nobuyuki
    Takeda, Yasuo
    Yamamoto, Osamu
    [J]. SOLID STATE IONICS, 2011, 192 (01) : 326 - 329
  • [50] High Ag+ Ion Conduction in NASICON-Type Solids
    Tamura, Shinji
    Highchi, Takatoshi
    Imanaka, Nobuhito
    [J]. ELECTROCHEMICAL AND SOLID STATE LETTERS, 2010, 13 (09) : F13 - F15
12345