Tuning the metal-based redox potentials of manganese cis,cis-1,3,5-triaminocyclohexane complexes

被引：25

作者：

Lewis, EA

Smith, JRL ^{[1
]}

Walton, PH

Archibald, SJ

Foxon, SP

Giblin, GMP

机构：

[1] Univ York, Dept Chem, York YO10 5DD, N Yorkshire, England

[2] Glaxo Wellcome Res & Dev Ltd, Med Chem, Stevenage SG1 2NY, Herts, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2001年 / 08期

关键词：

D O I：

10.1039/b102103f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A selection of 5-substituted salicylaldehydes have been reacted with cis,cis-triaminocyclohexane to prepare a series of tri-imine and tri-amine ligands; cyclic voltammetry has been used to show that the electronic effect of the substituent has a marked and systematic effect on the Mn-III/Mn-IV and Mn-III/Mn-II redox potentials of their manganese complexes.

引用

页码：1159 / 1161

页数：3

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