Tuning the metal-based redox potentials of manganese cis,cis-1,3,5-triaminocyclohexane complexes

被引：25
|
作者：
Lewis, EA
Smith, JRL [1 ]
Walton, PH
Archibald, SJ
Foxon, SP
Giblin, GMP
机构：
[1] Univ York, Dept Chem, York YO10 5DD, N Yorkshire, England
[2] Glaxo Wellcome Res & Dev Ltd, Med Chem, Stevenage SG1 2NY, Herts, England
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2001年 / 08期
关键词：
D O I：
10.1039/b102103f
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A selection of 5-substituted salicylaldehydes have been reacted with cis,cis-triaminocyclohexane to prepare a series of tri-imine and tri-amine ligands; cyclic voltammetry has been used to show that the electronic effect of the substituent has a marked and systematic effect on the Mn-III/Mn-IV and Mn-III/Mn-II redox potentials of their manganese complexes.
引用
收藏
页码：1159 / 1161
页数：3
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