Reactions of singlet excitons in tris-(8-hydroxyquinoline) aluminum

被引:7
|
作者
Sokolik, I [1 ]
Walser, AD [1 ]
Priestley, R [1 ]
Tang, CW [1 ]
Dorsinville, R [1 ]
机构
[1] EASTMAN KODAK CO,ROCHESTER,NY 14650
关键词
photoluminescence; time-resolved fast spectroscopy; organic semiconductors based on conjugated molecules;
D O I
10.1016/S0379-6779(96)04211-7
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Singlet excited state reactions in thin films of tris(8-hydroxyquinoline) aluminum (Alq(3)), a well known emitter for organic eledroluminescent devices, are described. Bimolecular recombination dominates the singlet exciton decay in pristine films at high intensities, thus decreasing the photoluminescence quantum efficiency and singlet lifetime. The measured rate constant of the singlet-singlet annihilation in Alq(3) films is gamma(SS) = (3.5+/-2.5) X 10(-11) cm(3) s(-1). The value of the diffusion coefficient of singlet excitons estimated from gamma(SS) is D-S = (1.2+/-0.8) X 10(-5) cm(2) s(-1).
引用
收藏
页码:921 / 922
页数:2
相关论文
共 50 条
  • [1] Bimolecular reactions of singlet excitons in tris(8-hydroxyquinoline) aluminum
    Sokolik, I
    Priestley, R
    Walser, AD
    Dorsinville, R
    Teng, CW
    [J]. APPLIED PHYSICS LETTERS, 1996, 69 (27) : 4168 - 4170
  • [2] Photoemission study of aluminum/tris-(8-hydroxyquinoline) aluminum and aluminum/LiF/tris-(8-hydroxyquinoline) aluminum interfaces
    Le, QT
    Yan, L
    Gao, YG
    Mason, MG
    Giesen, DJ
    Tang, CW
    [J]. JOURNAL OF APPLIED PHYSICS, 2000, 87 (01) : 375 - 379
  • [4] Synthesis and characterization of tris-(8-hydroxyquinoline)aluminum
    Li, HR
    Zhang, FJ
    Wang, YY
    Zheng, DS
    [J]. MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2003, 100 (01): : 40 - 46
  • [5] The triplet state in tris-(8-hydroxyquinoline)aluminum
    Cölle, M
    Gärditz, C
    Braun, M
    [J]. JOURNAL OF APPLIED PHYSICS, 2004, 96 (11) : 6133 - 6141
  • [6] Nonlinear Optical Properties of Tris-(8-Hydroxyquinoline)-Aluminum
    Derkowska-Zielinska, Beata
    [J]. 2016 18TH INTERNATIONAL CONFERENCE ON TRANSPARENT OPTICAL NETWORKS (ICTON), 2016,
  • [7] Charge carrier traps in tris-(8-hydroxyquinoline) aluminum
    Secu, M.
    Polosan, S.
    [J]. JOURNAL OF LUMINESCENCE, 2018, 194 : 91 - 95
  • [8] Evaluation of bulk trap density of tris-(8-hydroxyquinoline) aluminum
    Mizuo, S
    Tabatake, S
    Naka, S
    Okada, H
    Onnagawa, H
    [J]. JOURNAL OF APPLIED PHYSICS, 2002, 92 (03) : 1450 - 1452
  • [9] Tris-(8-hydroxyquinoline) aluminum nanoparticles prepared by vapor condensation
    Chiu, JJ
    Wang, WS
    Kei, CC
    Perng, TP
    [J]. APPLIED PHYSICS LETTERS, 2003, 83 (02) : 347 - 349
  • [10] Photoemission study of tris(8-hydroxyquinoline) aluminum/aluminum oxide/tris(8-hydroxyquinoline) aluminum interface
    Ding, Huanjun
    Zorba, Serkan
    Gao, Yongli
    Ma, Liping
    Yang, Yang
    [J]. Journal of Applied Physics, 2006, 100 (11):