Selenosilanes mediated stereoselective synthesis of polyfunctionalized organic molecules

被引：9

作者：

Degl'Innocenti, Alessandro ^{[1
]}

Capperucci, Antonella

Castagnoli, Giulio

Malesci, Irene

Tiberi, Caterina

Innocenti, Brunella

机构：

[1] Univ Florence, Dipartimento Chim Organ, I-50019 Sesto Fiorentino, Italy

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2008年 / 183卷 / 04期

关键词：

silyl-selenide; epoxides; episulfides; aziridines; selenoheterocycles;

D O I：

10.1080/10426500801900923

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Bis(trimethylsilyl)selenide (HMDSS) acts as an efficient reagent in the TBAF catalyzed reaction with different substituted epoxides, episulfides, and aziridines, leading to beta-functionalized diselenides in a highly regio- and stereoselective way. When using alpha-bromo alkyl ethers as trapping agent, 1,3-oxaselenolanes and 1,3-thiaselenolanes can be isolated, while 1,3-selenazolidines could be obtained through reduction of beta-amino diselenides followed by in situ treatment with different aldehydes.

引用

页码：966 / 969

页数：4

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