A new chiral diphosphine ligand and its asymmetric induction in catalytic hydroformylation of olefins

被引：38
|
作者：
Lu, SJ [1 ]
Li, XD [1 ]
Wang, AL [1 ]
机构：
[1] Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
来源：
CATALYSIS TODAY | 2000年 / 63卷 / 2-4期
基金：
中国国家自然科学基金;
关键词：
chiral diphosphine; asymmetric hydroformylation; rhodium catalyst;
D O I：
10.1016/S0920-5861(00)00500-9
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
A new chiral ligand, 1,6-anhydro-2,4-bis(diphenylphosphino)pyranose (ABDPP), was prepared from D-glucose. The ligand was used to prepare a chiral rhodium catalyst system for asymmetric hydroformylation of olefins. For vinyl acetate, the catalytic hydroformylation gave rather high yield (96%), high enantioselectivity (92% eel, and high regioselectivity (b/n = 95/5). But for styrene and norbornene, the results were not so good. The rather high sterioselectivity in the hydroformylation of vinyl acetate is explained in terms of the hydrogen bonding between OH group in the ligand molecule and the carbonyl group of vinyl acetate. (C) 2000 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：531 / 536
页数：6
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