Stabilisation of ions in unusual oxidation states and electron dynamics in oxide glasses

被引：0

作者：

Aleksandrov, AI ^{[1
]}

Prokofev, AL ^{[1
]}

Bubnov, NN ^{[1
]}

机构：

[1] RUSSIAN ACAD SCI, AN NESMEYANOV ORGANOELEMENT CPDS INST, MOSCOW 117813, RUSSIA

来源：

USPEKHI KHIMII | 1996年 / 65卷 / 06期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The results of studies on the stabilisation of ions in unusual oxidation states in oxide glasses are summarised. Special attention is given to the connection of such ion stabilisation with the processes of electron density transfer, and to the disproportionation reactions. The effect of reversible low-temperature disproportionation on niobium, titanium, vanadium, molibdenium, tungsten ions ets. is treated. The formation of metal clusters in glasses is also shown to be connected with disproportionation.

引用

页码：519 / 537

页数：19

共 50 条

[21] Influence of oxidation-Reduction conditions of synthesis on oxidation states of Cr, Mo, and Co Ions in high-silica glasses
E. K. Mamedov
Glass Physics and Chemistry, 2012, 38 : 386 - 391
[22] Influence of oxidation-Reduction conditions of synthesis on oxidation states of Cr, Mo, and Co Ions in high-silica glasses
Mamedov, E. K.
GLASS PHYSICS AND CHEMISTRY, 2012, 38 (04) : 386 - 391
[23] Rattling ions and the anomalous vibrational dynamics of glasses
D'Angelo, G.
Crupi, C.
Carini, G.
Vasi, C.
PHYSICAL REVIEW B, 2011, 84 (17):
[24] Dynamics of lithium ions in calcium bismuthate glasses
Dutta, A
Ghosh, A
JOURNAL OF CHEMICAL PHYSICS, 2005, 122 (23):
[25] Dynamics of mobile ions in crystals, glasses and melts
Funke, K
Roling, B
Lange, M
SOLID STATE IONICS, 1998, 105 (1-4) : 195 - 208
[26] Investigation of the oxidation states of Cu additive in colored borosilicate glasses by electron energy loss spectroscopy
Yang, Guang
Cheng, Shaodong
Li, Chao
Zhong, Jiasong
Ma, Chuansheng
Wang, Zhao
Xiang, Weidong
JOURNAL OF APPLIED PHYSICS, 2014, 116 (22)
[27] Investigation of the oxidation states of Cu additive in colored borosilicate glasses by electron energy loss spectroscopy
1600, American Institute of Physics Inc. (116):
[28] Relaxation dynamics in quantum electron glasses
Ovadyahu, Z.
PHYSICAL REVIEW LETTERS, 2007, 99 (22)
[29] METAL-IONS IN UNUSUAL VALENCY STATES
SELLERS, RM
JOURNAL OF CHEMICAL EDUCATION, 1981, 58 (02) : 114 - 118
[30] METAL-IONS IN UNUSUAL VALENCY STATES
SELLERS, RM
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1980, 180 (AUG): : 7 - CHED

← 1 2 3 4 5 →