Chloro[5,6-diphenyl-1,2,4-triazine-3(2H)thionato]dimethyltin(IV)

被引：0

作者：

López-Torres, E

Mendiola, MA

Pastor, CJ ^{[1
]}

机构：

[1] Univ Autonoma Madrid, Fac Ciencias Modulo C9, Serv Interdept Invest, E-28049 Madrid, Spain

[2] Univ Autonoma Madrid, Fac Ciencias Modulo C8, Dept Quim Inorgan, E-28049 Madrid, Spain

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2003年 / 59卷

关键词：

D O I：

10.1107/S1600536803015356

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The reaction between dichlorodimethyltin(IV) and 5-methoxy-5,6- diphenyl-4,5-dihydro-2H-1,2,4-triazine-3-thione yields the title complex, [SnClMe2(C15H10N3S)]. The coordination sphere of the Sn atom is formed by the S, amine N and Cl atoms and two methyl groups, giving a pentacoordinate geometry. The distances Sn - N = 2.525 (2) Angstrom, Sn - S = 2.4671 (7) Angstrom, Sn - C = 2.109 (3) and 2.111 (4) Angstrom, and Sn-Cl = 2.4220 (7) Angstrom are in the ranges expected for this type of complex. The coordination mode of the triazinethione ligand results in a four-membered chelate ring.

引用

页码：M713 / M714

页数：2

共 50 条

[31] 5,6-diphenyl-3-(pyrazin-2-yl)-1,2,4-triazine
Deng, H
Chen, CL
Zhang, H
Su, CY
Ji, LN
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2002, 58 : O1321 - O1322
[32] Chemical and Spectrophotometric Investigations of 3-Mercapto-5,6-diphenyl-1,2,4-triazine as a New Carboxyl Activating Group
Rajan, M. P.
ASIAN JOURNAL OF CHEMISTRY, 2009, 21 (09) : 7327 - 7336
[33] Rerefinement of dichloro[3-(1,10-phenanthrolin-2-yl)-5,6-diphenyl-1,2,4-triazine]copper(II) as an anhydrous structure
Ng, SW
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2004, 60 : M937 - M938
[34] EXTRACTION SPECTROPHOTOMETRIC DETERMINATION OF NICKEL IN STEELS AND ALUMINUM METAL WITH 3-(2-PYRIDYL)-5,6-DIPHENYL-1,2,4-TRIAZINE AND ETHYL TETRABROMOPHENOLPHTHALEIN
SAKAI, T
OHNO, N
ICHINOBE, N
SASAKI, H
ANALYTICA CHIMICA ACTA, 1989, 221 (01) : 109 - 115
[35] EXTRACTIVE SPECTROPHOTOMETRIC DETERMINATION OF PALLADIUM(II) IN DENTAL ALLOYS WITH 3-(2-PYRIDYL)-5,6-DIPHENYL-1,2,4-TRIAZINE AND TETRABROMOPHENOLPHTHALEIN ETHYLESTER
SAKAI, T
OHNO, N
MORI, T
SASAKI, H
BUNSEKI KAGAKU, 1988, 37 (09) : 488 - 491
[36] SYNTHESIS OF 1,2,4-TRIAZINE-3,5(2H,4H)-DIONES CONTAINING ELECTRONEGATIVE SUBSTITUENTS IN POSITION-6
FARKAS, J
COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 1983, 48 (09) : 2676 - 2681
[37] Cobalt(II, III) and copper(II) complexes of 3-(2-furylidene) hydrazino-5,6-diphenyl-1,2,4-triazine
Kandil, SS
Ali, GY
El-Dissouky, A
TRANSITION METAL CHEMISTRY, 2002, 27 (04) : 398 - 406
[38] Cobalt(II, III) and copper(II) complexes of 3-(2-furylidene) hydrazino-5,6-diphenyl-1,2,4-triazine
Samir S. Kandil
Gamila Y. Ali
Ali El-Dissouky
Transition Metal Chemistry, 2002, 27 : 398 - 406
[39] The use of 3-(2-pyridyl)-5,6-diphenyl-1,2,4-triazine as a precolumn derivatizing reagent in HPLC determination for Fe(II) in natural samples
Zhu, Weihuang
Wu, Fengchang
Zheng, Jian
Liu, Congqiang
ANALYTICAL SCIENCES, 2007, 23 (11) : 1291 - 1296
[40] STUDIES ON AS-TRIAZINE DERIVATIVES .2. A RING-CLEAVAGE REACTION OF 3-TRICHLOROMETHYL-5,6-DIPHENYL-1,2,4-TRIAZINE AND RELATED-COMPOUNDS
KONNO, S
YOKOYAMA, M
YAMANAKA, H
HETEROCYCLES, 1982, 19 (10) : 1865 - 1868

← 1 2 3 4 5 →