Chloro[5,6-diphenyl-1,2,4-triazine-3(2H)thionato]dimethyltin(IV)

被引：0

作者：

López-Torres, E

Mendiola, MA

Pastor, CJ ^{[1
]}

机构：

[1] Univ Autonoma Madrid, Fac Ciencias Modulo C9, Serv Interdept Invest, E-28049 Madrid, Spain

[2] Univ Autonoma Madrid, Fac Ciencias Modulo C8, Dept Quim Inorgan, E-28049 Madrid, Spain

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2003年 / 59卷

关键词：

D O I：

10.1107/S1600536803015356

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The reaction between dichlorodimethyltin(IV) and 5-methoxy-5,6- diphenyl-4,5-dihydro-2H-1,2,4-triazine-3-thione yields the title complex, [SnClMe2(C15H10N3S)]. The coordination sphere of the Sn atom is formed by the S, amine N and Cl atoms and two methyl groups, giving a pentacoordinate geometry. The distances Sn - N = 2.525 (2) Angstrom, Sn - S = 2.4671 (7) Angstrom, Sn - C = 2.109 (3) and 2.111 (4) Angstrom, and Sn-Cl = 2.4220 (7) Angstrom are in the ranges expected for this type of complex. The coordination mode of the triazinethione ligand results in a four-membered chelate ring.

引用

页码：M713 / M714

页数：2

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