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Post-polymerization functionalization of linear polyglycidol with diethyl vinylphosphonate

被引：21
|
作者：
Koehler, Jens
Keul, Helmut [1 ]
Moeller, Martin
机构：
[1] Rhein Westfal TH Aachen, Inst Tech & Macromol Chem, D-52056 Aachen, Germany
来源：
CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 28期
关键词：
SELF-ASSEMBLED MONOLAYERS; POLY(VINYLPHOSPHONIC ACID); CARBON-STEEL; PHOSPHONATE; ESTER; DEALKYLATION; MOLECULES;
D O I：
10.1039/c1cc12484f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In this communication we report on the base catalyzed Michael addition of the hydroxy methyl side groups in polyglycidol to diethyl vinyl phosphonate. Hydrolysis of the diethyl phosphonato ethyl side groups with bromotrimethylsilane leads to a new class of polyglycidols with pendant phosphonic acid groups.
引用
收藏
页码：8148 / 8150
页数：3
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