Post-polymerization functionalization of linear polyglycidol with diethyl vinylphosphonate

被引：21
|
作者：
Koehler, Jens
Keul, Helmut [1 ]
Moeller, Martin
机构：
[1] Rhein Westfal TH Aachen, Inst Tech & Macromol Chem, D-52056 Aachen, Germany
来源：
CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 28期
关键词：
SELF-ASSEMBLED MONOLAYERS; POLY(VINYLPHOSPHONIC ACID); CARBON-STEEL; PHOSPHONATE; ESTER; DEALKYLATION; MOLECULES;
D O I：
10.1039/c1cc12484f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In this communication we report on the base catalyzed Michael addition of the hydroxy methyl side groups in polyglycidol to diethyl vinyl phosphonate. Hydrolysis of the diethyl phosphonato ethyl side groups with bromotrimethylsilane leads to a new class of polyglycidols with pendant phosphonic acid groups.
引用
收藏
页码：8148 / 8150
页数：3
相关论文
共 50 条
  • [1] Post-polymerization functionalization of polyolefins
    Boaen, NK
    Hillmyer, MA
    [J]. CHEMICAL SOCIETY REVIEWS, 2005, 34 (03) : 267 - 275
  • [2] Catalytic synthesis and post-polymerization functionalization of conjugated polyisoprene
    Gramlich, William M.
    Hillmyer, Marc A.
    [J]. POLYMER CHEMISTRY, 2011, 2 (09) : 2062 - 2067
  • [3] Tailoring Polyethers for Post-polymerization Functionalization by Cross Metathesis
    Morrison, Stephen D.
    Liskamp, Rob M. J.
    Prunet, Joelle
    [J]. ORGANIC LETTERS, 2018, 20 (08) : 2253 - 2256
  • [4] Overview on Post-Polymerization Functionalization of Butyl Rubber and Properties
    Behera, Prasanta Kumar
    Kumar, Amit
    Mohanty, Subhra
    Gupta, Virendra Kumar
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2022, 61 (46) : 16910 - 16923
  • [5] Post-polymerization functionalization of aliphatic polycarbonates using click chemistry
    Hassan, Mohsin
    Bhat, Gulzar A.
    Darensbourg, Donald J.
    [J]. POLYMER CHEMISTRY, 2024, 15 (18) : 1803 - 1820
  • [6] Amphiphilic block copolymers by a combination of anionic polymerization and selective post-polymerization functionalization
    Kaditi, Eleni
    Mountrichas, Grigoris
    Pispas, Stergios
    [J]. EUROPEAN POLYMER JOURNAL, 2011, 47 (04) : 415 - 434
  • [7] Organocatalytic ROP of functional cyclic carbonates and their post-polymerization functionalization
    Tempelaar, Sarah
    Mespouille, Laetitia
    Dubois, Philippe
    Dove, Andrew P.
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2011, 242
  • [8] Polyethylene Containing Triblock Copolymers Synthesized by Post-polymerization Functionalization
    Yan, Tianwei
    Guironnet, Damien
    [J]. MACROMOLECULES, 2020, 53 (11) : 4338 - 4344
  • [9] Revisiting the Zincke disulfide reaction for the post-polymerization functionalization of unsaturated polyolefins
    Dunst, Andreas
    Kienberger, Julia
    Slugovc, Christian
    [J]. POLYMER, 2014, 55 (22) : 5557 - 5560
  • [10] Living polymerization of a 2-alkylthio-2-oxazoline as a divergent platform for post-polymerization functionalization
    Wu, You-Chi
    Swager, Timothy
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2019, 258
12345