A recyclable catalyst for asymmetric transfer hydrogenation with a formic acid-triethylamine mixture in ionic liquid

被引:102
|
作者
Kawasaki, I [1 ]
Tsunoda, K [1 ]
Tsuji, T [1 ]
Yamaguchi, T [1 ]
Shibuta, H [1 ]
Uchida, N [1 ]
Yamashita, M [1 ]
Ohta, S [1 ]
机构
[1] Kyoto Pharmaceut Univ, Dept Funct Mol Chem, Yamashina Ku, Kyoto 6078414, Japan
关键词
D O I
10.1039/b500320b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel task-specific ionic ligand with an imidazolium salt moiety was synthesized, and its catalytic ability and recyclability for asymmetric transfer hydrogenation of acetophenone derivatives with a formic acid - triethylamine azeotropic mixture in an ionic liquid [ bmim][PF6] was examined.
引用
收藏
页码:2134 / 2136
页数:3
相关论文
共 50 条
  • [11] Green Synthesis of (R)-Terbutaline for Recyclable Catalytic Asymmetric Transfer Hydrogenation in Ionic Liquids
    Uchimoto, Hitomi
    Ikeda, Miki
    Tanida, Saori
    Ohhashi, Kayo
    Chihara, Yoshiko
    Shigeta, Takashi
    Arimitsu, Kenji
    Yamashita, Masayuki
    Nishide, Kiyoharu
    Kawasaki, Ikuo
    CHEMICAL & PHARMACEUTICAL BULLETIN, 2017, 65 (04) : 389 - 395
  • [12] Recyclable, supported, and homogeneous Noyori-Ikariya catalyst for asymmetric transfer hydrogenation in water
    Dauphinais, Maxime
    Charette, Andre
    Zimbron, Jeremy M.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2015, 250
  • [13] Asymmetric hydrogenation and catalyst recycling using ionic liquid and supercritical carbon dioxide
    Brown, RA
    Pollet, P
    McKoon, E
    Eckert, CA
    Liotta, CL
    Jessop, PG
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (06) : 1254 - 1255
  • [14] Asymmetric hydrogenation of aromatic ketones by new recyclable ionic tagged ferrocene-ruthenium catalyst system
    Xu, Di
    Zhou, Zhi-Ming
    Dai, Li
    Tang, Li-Wei
    Zhang, Jun
    BIOORGANIC & MEDICINAL CHEMISTRY LETTERS, 2015, 25 (09) : 1961 - 1964
  • [15] Effects of Surface Hydrophobicity on Catalytic Transfer Hydrogenation of Styrene with Formic Acid in a Biphasic Mixture
    Baghdady, Ezra A.
    Schwartz, Daniel K.
    Medlin, Will
    ACS APPLIED MATERIALS & INTERFACES, 2022, 14 (29) : 33457 - 33462
  • [16] A powerful bronsted acid catalyst for the organocatalytic asymmetric transfer hydrogenation of imines
    Hoffmann, S
    Seayad, AM
    List, B
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (45) : 7424 - 7427
  • [17] Stable Chiral Ruthenium Complex Catalyst Based on Polymer Ionic Liquid for Asymmetric Transfer Hydrogenation of Aliphatic Ketones in Water
    Li, Xinjuan
    Sun, Yanping
    Wang, Shangyue
    Jia, Xianbin
    ACS APPLIED POLYMER MATERIALS, 2020, 2 (03) : 1268 - 1275
  • [18] Transfer Hydrogenation Reaction Of Ketones And Formic Acid Under Hydrothermal Conditions Without A Catalyst
    Shen, Zheng
    Zhang, Yalei
    Zhou, Xuefei
    Wu, Bing
    Cao, Jianglin
    Jin, Fangming
    2ND INTERNATIONAL SYMPOSIUM ON AQUA SCIENCE, WATER RESOURCE AND LOW CARBON ENERGY, 2010, 1251 : 356 - 359
  • [19] Surfactant-accelerated asymmetric transfer hydrogenation with recyclable water-soluble catalyst in aqueous media
    Li, Jiahong
    Li, Xuefeng
    Ma, Yaping
    Wu, Jiashou
    Wang, Fei
    Xiang, Jing
    Zhu, Jin
    Wang, Qiwei
    Deng, Jingen
    RSC ADVANCES, 2013, 3 (06) : 1825 - 1834
  • [20] Advances in Catalyst Systems for the Asymmetric Hydrogenation and Transfer Hydrogenation of Ketones
    Stefane, Bogdan
    Pozgan, Franc
    CATALYSIS REVIEWS-SCIENCE AND ENGINEERING, 2014, 56 (01): : 82 - 174