Chemistry and structure of diterpenes of the Kaurane series: II. Reduction of isosteviol

被引：0

作者：

Al'fonsov, VA ^{[1
]}

Bakaleinik, GA ^{[1
]}

Gubaidullin, AT ^{[1
]}

Kataev, VE ^{[1
]}

Kovylyaeva, GI ^{[1
]}

Konovalov, AI ^{[1
]}

Litvinov, IA ^{[1
]}

Strobykina, IY ^{[1
]}

Strobykin, SI ^{[1
]}

Andreeva, OV ^{[1
]}

Korochkina, MG ^{[1
]}

机构：

[1] Russian Acad Sci, Kazan Res Ctr, AE Arbuzov Organ & Phys Chem Inst, Kazan, Tatarstan, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2000年 / 70卷 / 06期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Individual (4 alpha ,8 beta ,13 beta)-16-hydroxy-13-methyl-17-norkauran-18-oic acid was obtained by reduction with sodium borohydride of the tetracyclic kauranoid isosteviol isolated from Stevia rebaudiana Bertoni. The structure of the acid was established by X-ray diffraction analysis. The reduction of isosteviol was found to occur with a high stereocontrol.

引用

页码：953 / 960

页数：8

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