One-dimensional heterobimetallic complex bridged by 2,2'-bibenzimidazolate ligand

被引：0

作者：

Tadokoro, M

Takui, T

机构：

[1] Department of Chemistry, Faculty of Science, Osaka City University, Sumiyoshi-ku

来源：

MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 1996年 / 278卷

关键词：

D O I：

10.1080/10587259608033678

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

We have studied the crystal structure of a Cu(II) complex [Cu(bbim)(2)]((Pr4N)-Pr-n)(Na). MeOH (1) [where bbim(2-) = di-deprotonated 2,2'-bibenzimidazolate and (Pr4N+)-Pr-n = tetra-n-propylammonium cation] with two bbim(2-) as a di-deprotonated ligand for the first time. The X-ray crystal analysis shows that this Cu(II) complex consists of one-dimensional infinite chains with an alternate bonding sequence of Cu(II) and Na(I) bridged by the bbim(2-) ligand. Interestingly, Cu(II) ion in this complex has a distorted tetrahedral coordination structure. The interaction between these infinite chains is separated by (Pr4N+)-Pr-n cations.

引用

页码：225 / 228

页数：4

共 50 条

[41] One-dimensional oxalato-bridged metal(II) complexes with 4-amino-1,2,4-triazole as apical ligand
García-Couceiro, U
Castillo, O
Luque, A
García-Terán, JP
Beobide, G
Román, P
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2005, (21) : 4280 - 4290
[42] One-dimensional ladders and bridged columns.
Knoeppel, DW
Shore, SG
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1996, 212 : 161 - INOR
[43] Synthesis, Crystal Structure and Fluorescene of a One-dimensional Compound {CdI2（2,2′-bipy）}n
GUO Hong-Xua② DU Zi-Xianb YOU Xiu-Lia WANG Qing-Huaa a (Department of Chemistry & Environmental Scicence
Chinese Journal of Structural Chemistry, 2007, (02) : 211 - 213
[44] Synthesis, crystal structure and fluorescene of a one-dimensional compound CdI2(2,2′-bipy)}n
Guo Hong-Xu
Du Zi-Xian
You Xiu-Li
Wang Qing-Hua
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2007, 26 (02) : 211 - 213
[45] ONE-DIMENSIONAL, 2-DIMENSIONAL, AND 3-DIMENSIONAL COMPUTER ANIMATION OF COMPLEX VIBRATION
MONTGOMERY, DE
WEST, RL
MODAL ANALYSIS-THE INTERNATIONAL JOURNAL OF ANALYTICAL AND EXPERIMENTAL MODAL ANALYSIS, 1995, 10 (01): : 1 - 18
[46] ONE-DIMENSIONAL CONDUCTION - 2 DIMENSIONAL PROBLEM
BERNASCO.J
ZELLER, HR
KUSE, D
RICE, MJ
JOURNAL OF PHYSICS PART C SOLID STATE PHYSICS, 1972, 5 (11): : L127 - +
[47] The first heterobimetallic one dimensional cyano bridged nitrosyl complex containing an alkaline earth metal:: synthesis, characterization and crystal structure of the complex [Sr(Phen)2(DMF)2][Fe(NO)(CN)5]
RoyChowdhury, S
Komiyama, T
Yukawa, Y
Bhattacharyya, R
INORGANIC CHEMISTRY COMMUNICATIONS, 2004, 7 (10) : 1117 - 1119
[48] One-dimensional lanthanide chain bridged by nitronyl nitroxide radical ligand: structure and magnetic properties
Dong, Hui Yang
Zhu, Me
2020 INTERNATIONAL CONFERENCE ON ENERGY, ENVIRONMENT AND BIOENGINEERING (ICEEB 2020), 2020, 185
[49] ONE-DIMENSIONAL MODEL DESCRIBING COMPLEX TOPOLOGICAL DEFECTS IN 2-DIMENSIONAL ANTIFERROMAGNETS
KOVALEV, AS
FIZIKA NIZKIKH TEMPERATUR, 1994, 20 (10): : 1034 - 1049
[50] Cyano-bridged gadolinium-tungstate bimetallic one-dimensional chains with a dimethylacetamide ligand
Kosaka, Wataru
Hashimoto, Kazuhito
Ohkoshi, Shin-ichi
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2007, 80 (12) : 2350 - 2356

← 1 2 3 4 5 →