The N,N′-dioxide/Ni(II)-catalyzed asymmetric inverse-electron-demand hetero-Diels-Alder reaction of methyleneindolinones with hetero-substituted alkenes

被引：0

作者：

Zhou, Yuhang ^{[1
]}

Lin, Lili ^{[1
]}

Yin, Chengkai ^{[1
]}

Wang, Zhengmeng ^{[1
]}

Liu, Xiaohua ^{[1
]}

Feng, Xiaoming ^{[1
]}

机构：

[1] Sichuan Univ, Key Lab Green Chem & Technol, Minist Educ, Coll Chem, Chengdu 610064, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 58期

基金：

中国国家自然科学基金;

关键词：

BETA; GAMMA-UNSATURATED ALPHA-KETOESTERS; 1,3-DIPOLAR CYCLOADDITION REACTION; HIGHLY ENANTIOSELECTIVE SYNTHESIS; DIHYDROPYRAN-FUSED INDOLES; BINARY-ACID CATALYSIS; OXINDOLES; COMPLEX; CONSTRUCTION; MOIETIES; LIGANDS;

D O I：

10.1039/C5CC04245C

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The highly efficient catalytic asymmetric inverse-electron-demand hetero-Diels-Alder reaction of methyleneindolinones with hetero-substituted alkenes has been accomplished under mild reaction conditions. In the presence of chiral N,N'-dioxide/Ni(II) complexes, a wide range of optically active dihydropyran-fused indoles were obtained in up to 99% yield, >95 : 5 dr and 99% ee.

引用

页码：11689 / 11692

页数：4

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