Inverse-electron-demand hetero-Diels-Alder reaction of β,γ-unsaturated α-ketophosphonates catalyzed by prolinal dithioacetals

被引：109
|
作者：
Samanta, Sampak [1 ]
Krause, Jonathan [1 ]
Mandal, Tanmay [1 ]
Zhao, Cong-Gui [1 ]
机构：
[1] Univ Texas, Dept Chem, San Antonio, TX 78249 USA
来源：
ORGANIC LETTERS | 2007年 / 9卷 / 14期
关键词：
D O I：
10.1021/ol071097y
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Some novel prolinal dithioacetal derivatives were studied as catalysts for the inverse-electron-demand hetero-Diels-Alder reaction of enolizable aldehydes and beta,gamma-unsaturated alpha-ketophosphonates. The corresponding 5,6-dihydro-4H-pyran-2-ylphosphonates were obtained in good ee values (up to 94% ee).
引用
收藏
页码：2745 / 2748
页数：4
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