Syntheses, structures, and fluxional behavior of tricarbonylmolybdenum(0) and trioxomolybdenum(VI) complexes of tris(2-pyridylmethyl)amine with one free arm

被引：14
|
作者：
Xu, L [1 ]
Sasaki, Y [1 ]
Abe, M [1 ]
机构：
[1] Hokkaido Univ, Grad Sch Sci, Div Chem, Sapporo, Hokkaido 0600810, Japan
来源：
CHEMISTRY LETTERS | 1999年 / 02期
关键词：
D O I：
10.1246/cl.1999.163
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The Mo(0) and Mo(VI) complexes of tris(2-pyridylmethyl)amine (tpa), Mo(CO)(3)(tpa) and Mo(O)(3)(tpa). H2O, were synthesized. Structural analyses revealed tridentate coordination of rpa in both compounds. The fluxional behavior of both species was investigated by variable-temperature H-1 NMR spectroscopy.
引用
收藏
页码：163 / 164
页数：2
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