A series of oxorhenium(V) complexes containing tridentate tris(2-pyridylmethyl)amine bearing one free 2-pyridylmethyl arm

被引：31
|
作者：
Sugimoto, H [1 ]
Sasaki, Y [1 ]
机构：
[1] HOKKAIDO UNIV, GRAD SCH SCI, DIV CHEM, KITA KU, SAPPORO, HOKKAIDO 060, JAPAN
来源：
CHEMISTRY LETTERS | 1997年 / 06期
关键词：
D O I：
10.1246/cl.1997.541
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Tris (2-pyridylmethyl) amine (tpa) coordinates to oxorhenium(V) with two pyridyl and one amino nitrogen atoms leaving one 2-pyridylmethyl arm uncoordinated, giving a series of complexes, [Re(O)(L)(eta(3)-tpa)](+) (L is chelating dianion), due to strong trans influence of the oxo ligand.
引用
收藏
页码：541 / 542
页数：2
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