Water-repellent finishing of cotton fabrics by ultraviolet curing

被引：35
|
作者：
Ferrero, F.
Periolatto, M.
Sangermano, M.
Songia, M. Bianchetto
机构：
[1] Politecn Torino, Dipartimento Sci Mat & Ingn Chim, I-10129 Turin, Italy
[2] CNR ISMAC, Inst Macromol Studies, I-13900 Biella, Italy
来源：
JOURNAL OF APPLIED POLYMER SCIENCE | 2008年 / 107卷 / 02期
关键词：
cationic polymerization; photopolymerization; radical polymerization; silicones;
D O I：
10.1002/app.27110
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Cotton fabrics were water-repellent-finished by radical ultraviolet curing of silicone and urethane acrylates with different formulations. The fabrics were impregnated with undiluted resins and with toluene solutions or water emulsions. Moreover, cationic ultraviolet-curable systems were also investigated, such as an epoxy-functional polysiloxane and mixtures of an epoxy resin with hydroxyl-containing silicone additives. The gel content and polymerization yield were considered for the ultraviolet-curing process evaluation. Water-resistance properties were determined in terms of the contact angle, wettability, moisture adsorption, and water vapor permeability measurements, whereas the morphology and surface composition of treated fabrics were examined with scanning electron microscopy and energy-dispersive X-ray analysis. (C) 2007 Wiley Periodicals, Inc.
引用
收藏
页码：810 / 818
页数：9
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