Solvent-Induced Controllable Synthesis, Single-Crystal to Single-Crystal Transformation and Encapsulation of Alq3 for Modulated Luminescence in (4,8)-Connected Metal-Organic Frameworks

被引：139
|
作者：
Lan, Ya-Qian [1 ,2 ]
Jiang, Hai-Long [1 ]
Li, Shun-Li [2 ]
Xu, Qiang [1 ]
机构：
[1] Natl Inst Adv Ind Sci & Technol, Ikeda, Osaka 5638577, Japan
[2] NE Normal Univ, Fac Chem, Changchun 130024, Peoples R China
来源：
INORGANIC CHEMISTRY | 2012年 / 51卷 / 14期
关键词：
COORDINATION POLYMERS; HYDROGEN STORAGE; PORE-SIZE; SEPARATION; EXCHANGE; DESIGN; LIGAND; CADMIUM(II); ADSORPTION; ZINC(II);
D O I：
10.1021/ic202635a
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
In this work, for the first time, we have systematically demonstrated that solvent plays crucial roles in both controllable synthesis of metal-organic frameworks (MOFs) and their structural transformation process. With solvent as the only variable, five new MOFs with different structures have been constructed, in which one MOF undergoes solvent-induced single-crystal to single-crystal (SCSC) transformation that involves not only solvent exchange but also the cleavage and formation of coordination bonds. Particularly, a significant crystallographic change has been realized through an unprecedented three-step SCSC transformation process. Furthermore, we have demonstrated that the obtained MOF could be an excellent host for chromophores such as Alq3 for modulated luminescent properties.
引用
收藏
页码：7484 / 7491
页数：8
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