The electrochemical properties of templated and activated mesoporous carbons produced from coal pitch

被引:0
|
作者
Zhou Ying [1 ]
Song Xiao-na [1 ]
Shu Cheng [1 ]
Qiu Jie-shan [1 ,2 ]
机构
[1] Dalian Univ Technol, Carbon Res Lab, Ctr Nano Mat & Sci, Sch Chem Engn,State Key Lab Fine Chem, Dalian 116024, Peoples R China
[2] Key Lab Micro Nano Technol & Syst Liaoning Prov, Dalian 116024, Peoples R China
基金
中国国家自然科学基金;
关键词
Coal pitch; Template method; Activation; Mesoporous carbon; Electrochemical properties; POROUS CARBONS; PORE STRUCTURE; CAPACITANCE;
D O I
暂无
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Mesoporous carbons (MCs) were made from coal pitch derived from coal liquefaction residue with silica nanoparticles as template and CO2 as activation agent. The microstructure and electrochemical properties of the MCs were investigated with TEM, N-2 adsorption, an electrochemical workstation and a Land battery test system. Results show that the specific surface area increases with activation time at 900 degrees C under a CO2 flow rate of 100 mL.min(-1). The specific surface area of MC activated for 150 min is 1360 m(2).g(-1) while that of the un-activated one is 722 m(2).g(-1). The specific capacitance of the MC activated for 150 min is 135 F.g(-1) at a current density of 1000 mA.g(-1) and the decrease in its specific capacitance is 7% after being charged and discharged 10000 times.
引用
收藏
页码:187 / 191
页数:5
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