Organically Templated (3,4)-Connected Zn(II) Compound: Synthesis, Structure, and Luminescence

被引：2

作者：

Qiao, Yan-Hui ^{[1
]}

An, Zhe ^{[1
]}

机构：

[1] Guangdong Univ Petrochem Technol, Sch Chem Life & Sci, Maoming 525000, Guangdong, Peoples R China

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2016年 / 46卷 / 06期

关键词：

zinc(II); template synthesis; pillar-layered framework; luminescence; FRAMEWORK; PHOTOLUMINESCENCE; LAYER;

D O I：

10.1080/15533174.2014.989616

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Urothermal reactions of isophthalic acid (H(2)mbdc), 1,2,4-triazole (Htrz) with Zn(NO3)(2)center dot 6H(2)O produced a new compound, namely [Zn(mbdc)(0.)5(trz)](n)center dot n(e-urea) (1, H(2)mbdc = isophthalic acid, Htrz = 1,2,4-triazole, e-urea = ethyleneurea). The title compound crystallized in orthorhombic Pnma space group with a = 10.0327(6), b = 25.6510(12), c = 9.5121(8) angstrom, alpha = 90 degrees, beta = 90 degrees, gamma = 90 degrees, V D 2447.9(3) angstrom(3), C9H10N5O3Zn, M-r = 301.61, Z = 8, D-c = 1.637 g/cm(3), F(000) = 1612, mu = 2.015 mm(1), the final R = 0.071, and wR = 0.1895 for 2202 observed reflections (I > 2 sigma(I)). Single-crystal X-ray structural analysis reveals that compound 1 is a (3,4)connected 3D pillar-layered framework templated by e-urea molecules. Moreover, the thermal stability and luminescent property of 1 were also investigated in this work.

引用

页码：936 / 939

页数：4

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