One-pot mechanochemical synthesis to encapsulate functional guests into a metal-organic framework for proton conduction

被引：17

作者：

Wang, Yang ^{[1
]}

Lu, Ying ^{[1
]}

Li, Zhuo ^{[1
]}

Sun, Xiu-Wei ^{[1
]}

Zhang, Wan-Yu ^{[1
]}

Zhang, Shan ^{[1
]}

Wang, Jie ^{[1
]}

Dang, Tian-Yi ^{[1
]}

Zhang, Zhong ^{[1
]}

Liu, Shu-Xia ^{[1
]}

机构：

[1] Northeast Normal Univ, Coll Chem, Key Lab Polyoxometalate & Reticular Mat Chem, Minist Educ, Changchun 130024, Jilin, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2021年 / 57卷 / 71期

基金：

中国国家自然科学基金;

关键词：

IMIDAZOLE; CRYSTALLINE;

D O I：

10.1039/d1cc03482k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Through one-pot mechanochemical synthesis, a series of guests [imidazole, (aminomethyl)phosphonic acid, urea and sulfamic acid] are rapidly encapsulated into the pores of MOF NENU-3 while the MOF is formed. The synthesis of a MOF loaded with functional guests that used to take several days and require a multistep procedure can now be completed in one step within several minutes. The proton conductivities of the obtained composites increased by 2-3 orders of magnitude compared with NENU-3.

引用

页码：8933 / 8936

页数：4

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