One-pot mechanochemical synthesis to encapsulate functional guests into a metal-organic framework for proton conduction

被引:17
|
作者
Wang, Yang [1 ]
Lu, Ying [1 ]
Li, Zhuo [1 ]
Sun, Xiu-Wei [1 ]
Zhang, Wan-Yu [1 ]
Zhang, Shan [1 ]
Wang, Jie [1 ]
Dang, Tian-Yi [1 ]
Zhang, Zhong [1 ]
Liu, Shu-Xia [1 ]
机构
[1] Northeast Normal Univ, Coll Chem, Key Lab Polyoxometalate & Reticular Mat Chem, Minist Educ, Changchun 130024, Jilin, Peoples R China
基金
中国国家自然科学基金;
关键词
IMIDAZOLE; CRYSTALLINE;
D O I
10.1039/d1cc03482k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Through one-pot mechanochemical synthesis, a series of guests [imidazole, (aminomethyl)phosphonic acid, urea and sulfamic acid] are rapidly encapsulated into the pores of MOF NENU-3 while the MOF is formed. The synthesis of a MOF loaded with functional guests that used to take several days and require a multistep procedure can now be completed in one step within several minutes. The proton conductivities of the obtained composites increased by 2-3 orders of magnitude compared with NENU-3.
引用
收藏
页码:8933 / 8936
页数:4
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