Supramolecular compounds with three-dimensional hydrogen-bonded network [M(H2O)6](HL)2 (H2L=1-(4-Hydroxyphenyl)-5-thioacetatetetrazole, M=MnII, CoII, NiII and ZnII):: Synthesis, characterization and structures

被引：0
|
作者：
Mang Shu-Guang [1 ]
Feng Yun-Long [1 ]
Wen Yi-Hang [1 ]
机构：
[1] Zhejiang Normal Univ, Inst Phys Chem, Zhejiang Key Lab React Chem Solid Surfaces, Jinhua 321004, Zhejiang, Peoples R China
来源：
CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2008年 / 24卷 / 04期
关键词：
M-II compounds; supramolecular compounds; hydrogen bonds; pi-pi stacking interactions; crystal structure;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reactions of several divalent transition metals with 1-(4-Hydroxyphenyl)-5-thioacetatetetrazole (H2L) were studied in aqueous solution. Mn-II, Co-II, Ni-II, and Zn-II produced ionic products of general formula [M(H2O)(6)](HL)(2). The four compounds were characterized by crystallographic methods. And the results have shown that their crystals are isostructural and belong to the triclinic P (1) over bar space group. The metal center in each compound is six-coordinated, forming an ideal octahedral geometry. These neutral formula units make unique three-dimensional supramolecular architectures through hydrogen bonding (M-OH2 center dot center dot center dot O-C) and offset-panel pi-pi stacking interactions and stabilized by electrostatic force.
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页码：581 / 585
页数：5
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