Advantages of organophosphorus synthesis in ionic liquids:: "Green" approaches to useful phosphorus-substituted building blocks

被引：8

作者：

Odinets, I. L. ^{[1
]}

Matveeva, E. V. ^{[1
]}

Sharova, E. V. ^{[1
]}

Artyushin, O. I. ^{[1
]}

Kozlov, V. A. ^{[1
]}

Vorob'eva, D. V. ^{[1
]}

Osipov, S. N.

Roechenthaler, G. V. ^{[2
]}

机构：

[1] RAS, AN Nesmeyanov Organoelement Cpds Inst, Moscow 117901, Russia

[2] Univ Bremen, Inst Inorgan & Phys Chem, D-2800 Bremen 33, Germany

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2008年 / 183卷 / 2-3期

关键词：

1,2,3-triazoles; amidation; azidoalkylphosphonates; carbamoylmethyl phoshine oxides; click chemistry; ionic liquids; nucleophilic displacement reactions; the Michaelis-Arbuzov reaction;

D O I：

10.1080/10426500701735130

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Novel examples concerning the application of ionic liquids as a promoting reaction media in organophosphorus chemistry are discussed. Imidazolium ionic liquids were found to accelerate the Michaelis-Arbuzov reaction allowing to perform it under very mild conditions. Both phosphonium and imidazolium ILs give the possibility to perform easily direct amidation of phosphotyl acetic acids by various amines. Nucleophilic displacement reaction in a series of bromoalkylphosphonates was carried out in quantitative yield to afford azidoalkylphosphonates using the [bmim][PF6]/H2O system.

引用

页码：383 / 388

页数：6

共 25 条

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