A catalytic application of Cu2O and CuO films deposited over fiberglass

被引:193
|
作者
Ramírez-Ortiza, J
Ogura, T
Medina-Valtierra, J [1 ]
Acosta-Ortiz, SE
Bosch, P
de los Reyes, JA
Lara, VH
机构
[1] Ctr Invest Opt, Unidad Ags Juan de Montoro 207, Aguascalientes 20000, Mexico
[2] Univ Autonoma Zacatecas, Fac Ciencias Quim, Zacatecas 98600, Mexico
[3] Univ Autonoma Guadalajara, Dept Quim, Guadalajara, Jalisco, Mexico
[4] Univ Autonoma Metropolitana Iztapalapa, Mexico City 09340, DF, Mexico
关键词
chemical vapor deposition (CVD); fiberglass; copper deposition; catalytic material; characterization study; ethanol oxidation;
D O I
10.1016/S0169-4332(00)00822-9
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
With the purpose of utilizing copper oxides over fiberglass as a novel catalyst material in oxidation reactions, we have used the chemical vapor deposition of 2,4-pentanedionate copper(II) as a precursor and fiberglass as substrate. The deposition of copper oxides was achieved in a horizontal-flow reactor using O-2 as carrier-reactant gas at several deposition temperatures. Copper species deposited on fiberglass were characterized by X-ray diffraction (XRD), UV-visible spectrophotometry (UV-VIs) and scanning electronic microscopy (SEM) techniques. The fiberglass coated with copper oxides showed a catalytic activity for the oxidation of ethanol into a stream of air at different temperatures in a pulse microreactor. (C) 2001 Elsevier Science B.V, All rights reserved.
引用
收藏
页码:177 / 184
页数:8
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