Side products formation in the synthesis of diazabicyclo 2.2.2]octane on zeolite ZSM-5

被引：3

作者：

Trejbal, Jiri ^{[1
]}

Petrisko, Miroslav ^{[1
]}

Pasek, Josef ^{[1
]}

机构：

[1] Inst Chem Technol, Dept Organ Technol, Prague 16628, Czech Republic

来源：

CHEMICAL ENGINEERING & TECHNOLOGY | 2007年 / 30卷 / 11期

关键词：

1,4-diazabicyclo[2.2.2]octane; ethylendiamine; zeolites;

D O I：

10.1002/ceat.200700189

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

A research investigation into the synthesis of 1,4-diazabicyclo[2.2.2] octane from ethylendiamine over zeolite ZSM-5 was carried out. A number of side products such as alkylpyrazines, alkylpiperazines and alkyl-1, 4-diazabicyclo [2.2.2.] octanes were identified in the reaction mixture. A chemical mechanism based on elimination, condensation, cracking and proton transfer reactions was proposed for the formation of these compounds.

引用

页码：1506 / 1511

页数：6

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