Combining Oxoammonium Cation Mediated Oxidation and Photoredox Catalysis for the Conversion of Aldehydes into Nitriles

被引：16
|
作者：
Nandi, Jyoti [1 ]
Witko, Mason L. [1 ]
Leadbeater, Nicholas E. [1 ]
机构：
[1] Univ Connecticut, Dept Chem, 55 North Eagleville Rd, Storrs, CT 06269 USA
来源：
SYNLETT | 2018年 / 29卷 / 16期
关键词：
photooxidation; nitriles; ammonium persulfate; oxoammonium cations; visible light; PRIMARY AMINES; TRANSITION-METAL; AQUEOUS AMMONIA; ALCOHOLS; CYANATION; TEMPO; SALT; FUNCTIONALIZATION; DERIVATIVES; ARYLATION;
D O I：
10.1055/s-0037-1610272
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A method to oxidize aromatic aldehydes to nitriles has been developed. It involves a dual catalytic system of 4-acetamido-TEMPO and visible-light photoredox catalysis. The reaction is performed using ammonium persulfate as both the terminal oxidant and nitrogen source.
引用
收藏
页码：2185 / 2190
页数：6
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