Differential and substrate-selective reactivity of calix[4]arene derivatives with cyclenyl-Zn(II) modifications at the upper rim

被引：26
|
作者：
Ozturk, G [1 ]
Akkaya, EU [1 ]
机构：
[1] Middle E Tech Univ, Dept Chem, TR-06531 Ankara, Turkey
来源：
ORGANIC LETTERS | 2004年 / 6卷 / 02期
关键词：
D O I：
10.1021/ol0360694
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
[GRAPHICS] Novel "cone conformation" calix[4]arene derivatives, carrying either one or two cyclen (1,4,7,10-tetra-azacyclododecane) moieties at the upper rim, have been synthesized. The hydrolytic activities of the Zn(II) complexes of these calixarenes were studied. A surprising behavior was observed with p-nitrophenylstearate; whereas the bis-cyclenyl-2Zn(II) complex showed negligible hydrolytic activity over the background, the mononuclear complex showed a significant 400-fold rate increase at pH 8.5.
引用
收藏
页码：241 / 243
页数：3
相关论文
共 40 条
  • [21] Anion-binding properties of two calix[4]arene derivatives containing two ferrocene imine or ferrocene amine units at the upper rim
    Shaabani, Behrouz
    Shaghaghi, Zohreh
    APPLIED ORGANOMETALLIC CHEMISTRY, 2011, 25 (04) : 317 - 322
  • [22] Clustering Zwitterionic Amino Acids at the Upper Rim of Cone Calix[4]arene Triggers the Selective Recognition of Gram-Negative Bacterial Envelope
    Rispoli, Francesco
    Moretti, Luca
    Vezzoni, Carlo Alberto
    Tosi, Eloisa
    Molteni, Linda
    Ciaramelli, Carlotta
    Marchio, Luciano
    Volpi, Stefano
    Baldini, Laura
    Sansone, Francesco
    Palmioli, Alessandro
    Airoldi, Cristina
    Casnati, Alessandro
    SMALL STRUCTURES, 2025,
  • [23] Spectroscopy and Microscopy Studies of the Recognition of Amino Acids and Aggregation of Proteins by Zn(II) Complex of Lower Rim Naphthylidene Conjugate of Calix[4]arene
    Chinta, Jugun Prakash
    Acharya, Amitabha
    Kumar, Amit
    Rao, Chebrolu P.
    JOURNAL OF PHYSICAL CHEMISTRY B, 2009, 113 (35): : 12075 - 12083
  • [24] Colorimetric and fluorimetric chemosensor based on upper rim-functionalized calix[4]arene for selective detection of fluoride ion" (vol 245, 118950, 2021)
    Nemati, Mohammad
    Hosseinzadeh, Rahman
    Mohadjerani, Maryam
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2022, 269
  • [25] Synthesis, characterization and electrochemical properties of two new calix[4]arene derivatives bearing two ferrocene imine or ferrocene amine units at the upper rim
    Shaabani, Behrouz
    Shaghaghi, Zohreh
    TETRAHEDRON, 2010, 66 (17) : 3259 - 3264
  • [26] Structural characterization and reactivity of Cu(II) complex of p-tert-butyl-calix[4]arene bearing two imine pendants at lower rim
    Dey, M
    Rao, CP
    Guionneau, P
    INORGANIC CHEMISTRY COMMUNICATIONS, 2005, 8 (11) : 998 - 1001
  • [27] Lower Rim Substituted p-tert-Butyl-Calix[4]arene. Part 15. Pb(II)-Ion-Selective Electrodes Based on p-tert-Butyl-calix[4]arene Thioamides
    Bochenska, Maria
    Guzinski, Marcin
    Kulesza, Joanna
    ELECTROANALYSIS, 2009, 21 (17-18) : 2054 - 2060
  • [28] A highly efficient and selective turn-on fluorescent sensor for Cu2+ ion based on calix[4]arene bearing four iminoquinoline subunits on the upper rim
    Li, Guang-Ke
    Xu, Zhen-Xiang
    Chen, Chuan-Feng
    Huang, Zhi-Tang
    CHEMICAL COMMUNICATIONS, 2008, (15) : 1774 - 1776
  • [29] Anion recognition properties of new upper-rim bis[rhenium(I) bipyridyl, ruthenium(II) bis(bipyridyl), cobaltocenium]calix[4]arene receptors dictated by lower-rim substituents
    Beer, PD
    Drew, MGB
    Hesek, D
    Shade, M
    Szemes, F
    CHEMICAL COMMUNICATIONS, 1996, (18) : 2161 - 2162
  • [30] Designing nanoporous crystalline materials by self-assembly:: 2D hydrogen-bonded networks from upper rim calix[4]arene diamide derivatives
    Baldini, Laura
    Sansone, Francesco
    Massera, Chiara
    Casnati, Alessandro
    Ugozzoli, Franco
    Ungaro, Rocco
    INORGANICA CHIMICA ACTA, 2007, 360 (03) : 970 - 980
1234