Synthesis, crystal structure and properties of a new lead fluoride borate, Pb3OBO3F

被引：17
|
作者：
Zhao, Wenwu [1 ,2 ]
Pan, Shilie [1 ]
Dong, Xiaoyu [1 ,2 ]
Li, Junjie [1 ]
Tian, Xuelin [1 ]
Fan, Xiaoyun [1 ]
Chen, Zhaohui [1 ,3 ]
Zhang, Fangfang [1 ]
机构：
[1] Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
[3] Xinjiang Univ, Phys & Chem Detecting Ctr, Urumqi 830046, Peoples R China
来源：
MATERIALS RESEARCH BULLETIN | 2012年 / 47卷 / 04期
基金：
中国国家自然科学基金;
关键词：
X-ray diffraction; Crystal structure; Optical properties; NONLINEAR-OPTICAL PROPERTIES; COORDINATION; GENERATION; PB;
D O I：
10.1016/j.materresbull.2012.01.019
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
A new compound, Pb3OBO3F, has been grown by the high temperature solution method from the PbO-PbF2-B2O3 system. It crystallizes in the orthorhombic system, space group Pbcm with unit-cell parameters a = 7.6313(14) angstrom, b = 6.5229(12) angstrom, c= 11.906(2) angstrom, Z = 4, volume = 592.66(19) angstrom(3). The structure of the compound is solved by the direct methods and refined to R-1 = 0.0528 and wR(2) = 0.1400. Pb3OBO3F consists of Pb(1)O3F tetrahedra, Pb(2)O-4 tetrahedra and BO3 triangles which build up the symmetrical chains extended along the c-axis. The powder X-ray diffraction pattern of the Pb3OBO3F has been measured. Functional groups presented in the sample were identified by Fourier transform infrared spectrum. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码：947 / 951
页数：5
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