Hydrogen peroxide oxidation of lignin model compounds catalyzed by a manganese(IV)-Me4DTNE complex

被引：0

作者：

Cui, Y ^{[1
]}

Chen, CL ^{[1
]}

Gratzl, JS ^{[1
]}

Patt, R ^{[1
]}

机构：

[1] N Carolina State Univ, Dept Wood & Paper Sci, Raleigh, NC 27695 USA

来源：

ADVANCES IN LIGNOCELLULOSICS CHEMISTRY FOR ECOLOGICALLY FRIENDLY PULPING AND BLEACHING TECHNOLOGIES | 1998年

关键词：

D O I：

暂无

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The kinetics of oxidation of 1-(3,4-dimethylphenyl)ethanol, 1-(3,4-dimethylphenyl)-1-propene (mixture of E, Z isomers), and E-diphenylethene with hydrogen peroxide catalyzed by [LMn(IV)(mu-O)(3)Mn(IV)](ClO4)(2), where L=1,2-bis-(4,7-dimethyl-1,4,7-triazacyclonon-1-yl)ethane was investigated. These lignin model compounds underwent pseudo-first order reaction with excess hydrogen peroxide. The reaction rate constants at various temperature and the activation energy of these reactions were reported in this poster.

引用

页码：389 / 392

页数：4

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