Methyltrioxorhenium: a new catalyst for the activation of hydrogen peroxide to the oxidation of lignin and lignin model compounds

被引：98
|
作者：
Crestini, C
Pro, P
Neri, V
Saladino, R
机构：
[1] Univ Roma Tor Vergata, Dipartimento Sci & Tecnol Chim, I-00133 Rome, Italy
[2] Univ Tuscia, Dipartimento Agrobiol & Agrochim, I-01100 Viterbo, Italy
来源：
BIOORGANIC & MEDICINAL CHEMISTRY | 2005年 / 13卷 / 07期
关键词：
D O I：
10.1016/j.bmc.2005.01.049
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
The oxidative degradation of lignin under totally chlorine free conditions is one of the most relevant targets for the design of environmental friendly pulping and bleaching industrial processes. Methyltrioxorhenium was found a powerful and promising catalyst for the oxidation of both phenolic and non-phenolic lignin model compounds by use of hydrogen peroxide as primary oxidant. Three different technical lignins, hydrolytic sugar cane lignin (SCL), red spruce kraft lignin (RSL) and a hardwood organo-solvent lignin (OSL), that are representative examples of widely diffused para-hydroxyphenyl-guaiacyl, guaiacyl and guaiacyl-syringyl lignins, were also extensively degraded under similar experimental conditions. (c) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码：2569 / 2578
页数：10
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