Surface modification of hematite photoanode films with rhodium

被引：6

作者：

Zhang Minglong ^{[1
,2
,3
]}

Luo Wenjun ^{[1
,2
]}

Li Zhaosheng ^{[1
,2
]}

Yu Tao ^{[1
]}

Zou Zhigang ^{[1
]}

机构：

[1] Nanjing Univ, Natl Lab Solid Microstruct, Ecomat & Renewable Energy Res Ctr, Nanjing 210093, Jiangsu, Peoples R China

[2] Nanjing Univ, Dept Mat Sci & Engn, Nanjing 210093, Jiangsu, Peoples R China

[3] Xuzhou Airforce Coll, Dept Airfield, Xuzhou 221000, Peoples R China

来源：

RARE METALS | 2011年 / 30卷

基金：

中国国家自然科学基金;

关键词：

hematite; photoelectrochemistry; solar energy storage; hydrogen; OXYGEN-EVOLVING CATALYST; WATER OXIDATION; ALPHA-FE2O3; ELECTRODES; FERRIC-OXIDE; NANOSTRUCTURE; SI;

D O I：

10.1007/s12598-011-0233-5

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The Si and Ti codoped hematite (alpha-Fe2O3) photoanode film was dripped by Na3RhCl6 center dot 12H(2)O alkaline solution to negatively shift the onset potential of alpha-Fe2O3 photoanode by similar to 200 mV. The photocurrent densities of as-treated and untreated alpha-Fe2O3 are 0.6, and 0.08 mA/cm(2), respectively at 0 V vs. Ag/AgCl in the electrolyte of 1 M NaOH aqueous solution under 500 W xenon illumination. The IPCE (incident photon to current efficiency) of the as-treated alpha-Fe2O3 is 5.2% at 365 nm, 0 V vs. Ag/AgCl. A plausible explanation is proposed for the enhanced alpha-Fe2O3 photoelectrochemical responses. The result shows that rhodium could be ranked as an efficient oxygen evolution catalyst.

引用

页码：38 / 41

页数：4

共 50 条

[1] Surface modification of hematite photoanode films with rhodium
Minglong Zhang
Wenjun Luo
Zhaosheng Li
Tao Yu
Zhigang Zou
[J]. Rare Metals, 2011, 30 : 38 - 41
[2] Promotional effects of cetyltrimethylammonium bromide surface modification on a hematite photoanode for photoelectrochemical water splitting
Li, Qian
Antony, Rajini P.
Wong, Lydia Helena
Ng, Dickon H. L.
[J]. RSC ADVANCES, 2015, 5 (121): : 100142 - 100146
[3] Tunable surface modification of a hematite photoanode by a Co(salen)-based cocatalyst for boosting photoelectrochemical performance
Wang, Ruiling
Kuwahara, Yasutaka
Mori, Kohsuke
Bu, Yuyu
Yamashita, Hiromi
[J]. CATALYSIS SCIENCE & TECHNOLOGY, 2020, 10 (06) : 1714 - 1723
[4] Surface modification of hematite photoanode by NiFe layered double hydroxide for boosting photoelectrocatalytic water oxidation
[J]. Han, Wei (whan@jlu.edu.cn), 1600, Elsevier Ltd (764):
[5] Surface modification of hematite photoanode by NiFe layered double hydroxide for boosting photoelectrocatalytic water oxidation
Zhu, Yukun
Zhao, Xiaoliang
Li, Junzhi
Zhang, Huawei
Chen, Shuai
Han, Wei
Yang, Dongjiang
[J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2018, 764 : 341 - 346
[6] Photoanode for solar water oxidation based on titania and hematite films
Sima, M.
Vasile, E.
Sima, A.
[J]. THIN SOLID FILMS, 2018, 658 : 7 - 11
[7] Critical role and modification of surface states in hematite films for enhancing oxygen evolution activity
Pyeon, Myeongwhun
Ruoko, Tero-Petri
Leduc, Jennifer
Goenuellue, Yakup
Deo, Meenal
Tkachenko, Nikolai V.
Mathur, Sanjay
[J]. JOURNAL OF MATERIALS RESEARCH, 2018, 33 (04) : 455 - 466
[8] Critical role and modification of surface states in hematite films for enhancing oxygen evolution activity
Myeongwhun Pyeon
Tero-Petri Ruoko
Jennifer Leduc
Yakup Gönüllü
Meenal Deo
Nikolai V. Tkachenko
Sanjay Mathur
[J]. Journal of Materials Research, 2018, 33 : 455 - 466
[9] A novel strategy for surface treatment on hematite photoanode for efficient water oxidation
Xi, Lifei
Chiam, Sing Yang
Mak, Wai Fatt
Tran, Phong D.
Barber, James
Loo, Say Chye Joachim
Wong, Lydia Helena
[J]. CHEMICAL SCIENCE, 2013, 4 (01) : 164 - 169
[10] Interface and surface engineering of hematite photoanode for efficient solar water oxidation
Chen, Xiangyan
Fu, Yanming
Hong, Liu
Kong, Tingting
Shi, Xiaobo
Wang, Guangxu
Qu, Le
Shen, Shaohua
[J]. JOURNAL OF CHEMICAL PHYSICS, 2020, 152 (24):

← 1 2 3 4 5 →