P,C,P-Pincer complexes of ruthenium based on ruthenocene and pentamethylruthenocene

被引：13
|
作者：
Safronov, S. V. [1 ]
Sheloumov, A. M. [1 ]
Kreindlin, A. Z. [1 ]
Kamyshova, A. A. [1 ]
Dolgushin, F. M. [1 ]
Smolyakov, A. F. [1 ]
Petrovskii, P. V. [1 ]
Ezernitskaya, M. G. [1 ]
Koridze, A. A. [1 ,2 ]
机构：
[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia
[2] I Javakhishvili Tbilisi State Univ, Dept Chem, GE-0128 Tbilisi, Georgia
来源：
RUSSIAN CHEMICAL BULLETIN | 2010年 / 59卷 / 09期
基金：
俄罗斯基础研究基金会;
关键词：
ruthenium; pincer complexes; ruthenocenes; pentamethylruthenocenes; diphosphines; carbonyls; X-ray diffraction analysis; PINCER COMPLEXES; PALLADIUM; FERROCENE;
D O I：
10.1007/s11172-010-0306-x
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The first ruthenocene- and pentamethylruthenocene-based ruthenium pincer complexes, RuCl(CO)[{2,5-(Bu-t 2PCH2)(2)C5H2}Ru(C5H5)] and RuCl(CO)[{2,5-(Bu-t 2PCH2)(2)C5H2}Ru-(C5Me5)], were synthesized by cyclometallation of {1,3-(Bu-t 2PCH2)(2)C5H2}Ru(C5H5) and {1,3-(Bu-t 2PCH2)(2)C5H2}Ru(C5Me5), respectively, with RuCl2(DMSO)(4) in 2-methoxyethanol and characterized by H-1 and P-31{H-1} NMR spectroscopy, and X-ray diffraction.
引用
收藏
页码：1740 / 1744
页数：5
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