Converting carbohydrates to bulk chemicals and fine chemicals over heterogeneous catalysts

被引:506
|
作者
Climent, Maria J. [1 ]
Corma, Avelino [1 ]
Iborra, Sara [1 ]
机构
[1] Univ Politecn Valencia, Inst Tecnol Quim UPV CSIC, Valencia 46022, Spain
关键词
LIQUID-PHASE DEHYDRATION; SUCROSE HYDROXYALKYL ETHERS; CATIONIC EXCHANGE RESINS; SOLID ACID CATALYSTS; LONG-TERM STABILITY; SELECTIVE OXIDATION; AEROBIC OXIDATION; GOLD CATALYSTS; GLUCOSE-OXIDATION; D-XYLOSE;
D O I
10.1039/c0gc00639d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this Critical Review, we discuss how carbohydrates can be transformed into a variety of chemicals through heterogeneous catalysis. We focus particularly on oxidation, reduction and dehydration of hexoses, as well as one-pot reactions of di- and polysaccharides. Most of the reactions involve heterogeneous catalysts, although some interesting homogeneously catalyzed processes are also included.
引用
收藏
页码:520 / 540
页数:21
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