Converting carbohydrates to bulk chemicals and fine chemicals over heterogeneous catalysts

被引：506

作者：

Climent, Maria J. ^{[1
]}

Corma, Avelino ^{[1
]}

Iborra, Sara ^{[1
]}

机构：

[1] Univ Politecn Valencia, Inst Tecnol Quim UPV CSIC, Valencia 46022, Spain

来源：

GREEN CHEMISTRY | 2011年 / 13卷 / 03期

关键词：

LIQUID-PHASE DEHYDRATION; SUCROSE HYDROXYALKYL ETHERS; CATIONIC EXCHANGE RESINS; SOLID ACID CATALYSTS; LONG-TERM STABILITY; SELECTIVE OXIDATION; AEROBIC OXIDATION; GOLD CATALYSTS; GLUCOSE-OXIDATION; D-XYLOSE;

D O I：

10.1039/c0gc00639d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this Critical Review, we discuss how carbohydrates can be transformed into a variety of chemicals through heterogeneous catalysis. We focus particularly on oxidation, reduction and dehydration of hexoses, as well as one-pot reactions of di- and polysaccharides. Most of the reactions involve heterogeneous catalysts, although some interesting homogeneously catalyzed processes are also included.

引用

页码：520 / 540

页数：21

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