Improved performance of dual-cured organosolv lignin-based epoxy acrylate coatings

被引:26
|
作者
Yan, Ru [1 ]
Liu, Yangyang [1 ]
Liu, Baijun [2 ]
Zhang, Yumei [1 ]
Zhao, Qi [1 ]
Sun, Zhaoyan [3 ]
Hu, Wei [1 ]
Zhang, Niaona [1 ]
机构
[1] Changchun Univ Technol, Coll Chem Engn, 2055 Yanan St, Changchun 130012, Jilin, Peoples R China
[2] Jilin Univ, Coll Chem, 2699 Qianjin St, Changchun 130012, Jilin, Peoples R China
[3] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Jilin, Peoples R China
基金
中国国家自然科学基金;
关键词
Organosolv lignin; epoxy acrylate; UV-cured; dual-cured; coatings; UV-CURABLE COATINGS; MECHANICAL-PROPERTIES; RESISTANT; STRENGTH; RESINS;
D O I
10.1016/j.coco.2018.04.006
中图分类号
TB33 [复合材料];
学科分类号
摘要
Organosolv lignin (OL) was used to synthesize organosolv-lignin-based epoxy acrylate (OLBEA) coatings. The reaction process was determined by epoxy and acid values. OLBEA coatings were prepared by dual (Ultraviolet (UV) and thermal) curing to achieve a deep and complete process. The structures of lignin-based epoxy (OLBE) and OLBEA were characterized by Fourier transform infrared spectroscopy (FTIR). The properties of the dualand UV-cured coatings were then compared by measuring gel content and mechanical properties. Results revealed that the dual-cured films had higher cross-linking degree and better mechanical properties than the UVcured films. The chemical resistance of the dual-cured coatings was also examined. The properties of OLBEA coatings obtained by dual curing were shown to be excellent and promising for wide-ranging applications.
引用
收藏
页码:52 / 56
页数:5
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