Detonation in the hydrogen-oxygen microfoam on the aqueous base

被引:3
|
作者
Kichatov, Boris [1 ,2 ]
Korshunov, Alexey [1 ,2 ]
Kiverin, Alexey [1 ]
Yakovenko, Ivan [1 ]
Gubernov, Vladimir [2 ]
Khomik, Sergey, V [3 ]
Medvedev, Sergey P. [3 ]
机构
[1] Russian Acad Sci, Joint Inst High Temp, Izhorskaya St 13 Bd 2, Moscow 125412, Russia
[2] Russian Acad Sci, Lebedev Phys Inst, Moscow 119991, Russia
[3] Russian Acad Sci, NN Semenov Fed Res Ctr Chem Phys, Moscow 119991, Russia
基金
俄罗斯科学基金会;
关键词
Detonation; Microfoam; Shock wave; Hydrogen; Bubble; FLAME ACCELERATION; PROPAGATION MECHANISM; GASEOUS DETONATION; H-2-O-2; DETONATION; SQUARE TUBE; SHOCK-WAVE; ROUND TUBE; TRANSITION; COMBUSTION; DEFLAGRATION;
D O I
10.1016/j.ijhydene.2019.10.049
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In the paper, the propagation of the detonation wave in the hydrogen-oxygen microfoam on the aqueous base is considered. Microfoam represents a two-phase system containing micron-sized gas bubbles filled with the hydrogen-oxygen mixture. These bubbles are dispersed in the water solution of surfactant (sodium dodecyl sulfate). The dependencies of detonation speed on the equivalence ratio and on the water content in the foam are obtained with the use of high-speed filming. It is found that the detonation speed slightly increases with the decrease in water content in the foam. Based on the pressure measurements, it is established that the detonation propagation in the foam is driven by relatively weak shock waves, which by themselves are not able to induce ignition of the hydrogen-oxygen mixture. To substantiate the fact of detonation existence in the micro- foam a hypothesis of the cumulative collapse of gas bubbles under the shock wave action is proposed. The estimation for detonation speed in microfoam is analytically derived on the basis of simple phenomenological representations. (C) 2019 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:31567 / 31578
页数:12
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