Novel rate equations describing isochronous chemical reactions

被引:0
|
作者
Calogero, F. [1 ,2 ]
Leyvraz, F. [3 ,4 ]
Sommacal, M. [1 ,2 ]
机构
[1] Univ Roma La Sapienza, Dipartimento Fis, Rome, Italy
[2] Ist Nazl Fis Nucl, Sez Roma, Rome, Italy
[3] Univ Los Andes, Dept Fis, Bogota, Colombia
[4] UNAM, Inst Ciencias Fis, Cuernavaca, Morelos, Mexico
关键词
Oscillatory chemical reactions; Rate equations; Isochronous systems;
D O I
10.1007/s10910-010-9784-1
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A simple mathematical model involving two first-order Ordinary Differential Equations (ODEs) with fourth-degree polynomial nonlinearities is introduced. The initial-value problem for this system of two ODEs is solved in terms of elementary functions: for an open set of initial data, this solution is isochronous, i.e., completely periodic with a fixed period (independent of the initial data); in the complementary set of initial data, it blows up at a finite time. This system is likely to be of applicative interest: for instance it models the time evolution of two chemical substances in a spatially homogeneous situation, provided this evolution is characterized by six appropriate chemical reactions whose rates are simply expressed in terms of three a priori arbitrary parameters, or alternatively by five appropriate reactions whose rates are simply expressed in terms of two a priori arbitrary parameters.
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页码:870 / 879
页数:10
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