Novel rate equations describing isochronous chemical reactions

被引:0
|
作者
Calogero, F. [1 ,2 ]
Leyvraz, F. [3 ,4 ]
Sommacal, M. [1 ,2 ]
机构
[1] Univ Roma La Sapienza, Dipartimento Fis, Rome, Italy
[2] Ist Nazl Fis Nucl, Sez Roma, Rome, Italy
[3] Univ Los Andes, Dept Fis, Bogota, Colombia
[4] UNAM, Inst Ciencias Fis, Cuernavaca, Morelos, Mexico
关键词
Oscillatory chemical reactions; Rate equations; Isochronous systems;
D O I
10.1007/s10910-010-9784-1
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A simple mathematical model involving two first-order Ordinary Differential Equations (ODEs) with fourth-degree polynomial nonlinearities is introduced. The initial-value problem for this system of two ODEs is solved in terms of elementary functions: for an open set of initial data, this solution is isochronous, i.e., completely periodic with a fixed period (independent of the initial data); in the complementary set of initial data, it blows up at a finite time. This system is likely to be of applicative interest: for instance it models the time evolution of two chemical substances in a spatially homogeneous situation, provided this evolution is characterized by six appropriate chemical reactions whose rates are simply expressed in terms of three a priori arbitrary parameters, or alternatively by five appropriate reactions whose rates are simply expressed in terms of two a priori arbitrary parameters.
引用
收藏
页码:870 / 879
页数:10
相关论文
共 50 条
  • [1] Novel rate equations describing isochronous chemical reactions
    F. Calogero
    F. Leyvraz
    M. Sommacal
    Journal of Mathematical Chemistry, 2011, 49 : 870 - 879
  • [2] Isochronous rate equations describing chemical reactions
    Calogero, F.
    Leyvraz, F.
    Sommacal, M.
    JOURNAL OF PHYSICS A-MATHEMATICAL AND THEORETICAL, 2010, 43 (43)
  • [3] Oscillatory and isochronous rate equations possibly describing chemical reactions
    Calogero, F.
    Leyvraz, F.
    JOURNAL OF PHYSICS A-MATHEMATICAL AND THEORETICAL, 2009, 42 (26)
  • [4] RELATIONS BETWEEN EQUATIONS DESCRIBING ELECTRODE PROCESSES ASSOCIATED WITH CHEMICAL REACTIONS
    GALUS, Z
    BULLETIN DE L ACADEMIE POLONAISE DES SCIENCES-SERIE DES SCIENCES CHIMIQUES, 1965, 13 (01): : 63 - &
  • [5] DIFFERENTIAL-EQUATIONS, DESCRIBING CHEMICAL-REACTIONS IN THE ULTRASONIC-FIELD
    DUBOVITSKII, VA
    KHIMICHESKAYA FIZIKA, 1987, 6 (05): : 672 - 676
  • [6] ON THE RATE OF CHEMICAL REACTIONS
    Wigner, Eugene
    Eyring, Henry
    SCIENTIFIC MONTHLY, 1937, 44 : 564 - 567
  • [7] Chemical kinetics equations describing water complex formations
    Klimeshina, Tatyana E.
    Rodimova, Olga B.
    24TH INTERNATIONAL SYMPOSIUM ON ATMOSPHERIC AND OCEAN OPTICS: ATMOSPHERIC PHYSICS, 2018, 10833
  • [8] The rate equations for consecutive reactions
    Hill, TL
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1942, 64 : 465 - 467
  • [9] Computer program for the equations describing the steady state of enzyme reactions
    Varon, R
    GarciaSevilla, F
    GarciaMoreno, M
    GarciaCanovas, F
    Peyro, R
    Duggleby, RG
    COMPUTER APPLICATIONS IN THE BIOSCIENCES, 1997, 13 (02): : 159 - 167
  • [10] APPLICATION OF EQUATIONS OF ELECTROMAGNETISM TO CHEMICAL RELAXATION PROBLEM - CALCULATION OF RATE CONSTANTS OF FAST REACTIONS
    RAMOS, MN
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1981, 20 (06): : 567 - 569