Interparticle force between like-charged colloidal systems: a numerical study

被引:3
|
作者
Terao, T [1 ]
Nakayama, T [1 ]
机构
[1] Hokkaido Univ, Dept Appl Phys, Sapporo, Hokkaido 0608628, Japan
关键词
interparticle forces; colloidal suspensions; primitive model; computer simulations;
D O I
10.1016/S0927-7757(00)00819-0
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We investigate numerically the interparticle force between like-charged colloidal systems confined by a cylinder. The interactions between colloidal particles are repulsive with smaller electrostatic coupling. On the contrary, the attractive interaction dominates with larger electrostatic coupling. These results clarify that the fluctuation effect beyond the Poisson-Boltzmann equation plays an important role, and the strength of the electrostatic coupling in an aqueous solution is an essential parameter to determine the effective potential between like-charged colloidal particles. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:299 / 304
页数:6
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